Bimetallic Lanthanum-Cerium-Loaded HZSM-5 Composite for Catalytic Deoxygenation of Microalgae-Hydrolyzed Oil into Green Hydrocarbon Fuels.

Mustafa Jawad Nuhma, Hajar Alias, Muhammad Tahir, Ali A Jazie

Abstract read

In one paragraph

Article in Molecules (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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5 · Who and what money

Authors and funding

4 authors.

Mustafa Jawad NuhmaDepartment of Chemical Engineering, School of Chemical and Energy Engineering, Universiti Teknologi Malaysia (UTM), Johor Bahru 81310, Johor, Malaysia.

Hajar AliasDepartment of Chemical Engineering, School of Chemical and Energy Engineering, Universiti Teknologi Malaysia (UTM), Johor Bahru 81310, Johor, Malaysia.

Muhammad TahirChemical and Petroleum Engineering Department, United Arab Emirates University (UAEU), Al Ain P.O. Box 15551, United Arab Emirates.

Ali A JazieChemical Engineering Department, College of Engineering, University of Al-Qadisiyah, Al-Diwaniyah City P.O. Box 1767, Iraq.

Funding

University of Technology Malaysia Q JI30000.2546.19H46

6 · The paper itself

Abstract

Due to their high lipid content, microalgae are one of the most significant sources of green hydrocarbons, which might help lessen the world's need for fossil fuels. Many zeolite-based catalysts are quickly deactivated by coke production and have a short lifetime. In this study, a bimetallic Lanthanum-Cerium (La-Ce)-modified HZSM-5 zeolite catalyst was synthesized through an impregnation method and was tested for the conversion of hydrolyzed oil into oxygen-free hydrocarbon fuels of high energy content. Initially, hydrolyzed oil (HO), the byproduct of the transesterification process, was obtained by the reaction of crude oil derived from Chlorella vulgaris microalgae and a methanol. Various catalysts were produced, screened, and evaluated for their ability to convert algal HO into hydrocarbons and other valuable compounds in a batch reactor. The performance of HZSM-5 was systematically tested in view of La-Ce loaded on conversion, yield, and selectivity. NH

Indexed as

CeriumChlorella vulgarisCokeMicroalgaeZeolitesHydrocarbonsLanthanumCeriumCokeHydrocarbonsLanthanumZeolitesChlorella vulgaris microalgaedeoxygenationhydrocarbonsHZSM-5 zeoliteLanthanum-Ceriumoxygenates

Identifiers

PMID36432121

DOI10.3390/molecules27228018

PMCPMC9697213

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