Evidence map›Paper›PMID 36431845›Full record

ArticleMolecules (Basel, Switzerland)2022

Promising Oxygen- and Nitrogen-Rich Azidonitramino Ether Plasticizers for Energetic Materials.

Dmitry B Vinogradov, Pavel V Bulatov, Evgeny Yu Petrov, Pavel S Gribov, Natalia N Kondakova, Natalia N Il'icheva, Evgenia R Stepanova, Anatoly P Denisyuk, Vladimir A Sizov, Valery P Sinditskii and 1 more

Abstract read
In one paragraph

Article in Molecules (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Dmitry B VinogradovZelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prosp., 119991 Moscow, Russia.
Pavel V BulatovZelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prosp., 119991 Moscow, Russia.
Evgeny Yu PetrovZelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prosp., 119991 Moscow, Russia.
Pavel S GribovZelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prosp., 119991 Moscow, Russia.ORCID 0000-0001-8300-1612
Natalia N KondakovaMendeleev University of Chemical Technology, 9 Miusskaya pl., 125047 Moscow, Russia.
Natalia N Il'ichevaMendeleev University of Chemical Technology, 9 Miusskaya pl., 125047 Moscow, Russia.
Evgenia R StepanovaMendeleev University of Chemical Technology, 9 Miusskaya pl., 125047 Moscow, Russia.
Anatoly P DenisyukMendeleev University of Chemical Technology, 9 Miusskaya pl., 125047 Moscow, Russia.
Vladimir A SizovMendeleev University of Chemical Technology, 9 Miusskaya pl., 125047 Moscow, Russia.ORCID 0000-0001-8616-1056
Valery P SinditskiiMendeleev University of Chemical Technology, 9 Miusskaya pl., 125047 Moscow, Russia.
Aleksei B SheremetevZelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prosp., 119991 Moscow, Russia.ORCID 0000-0002-3672-222X

Funding

The Ministry of Science and Higher Education of the Russian Federation 075-15-2020-803
6 · The paper itself

Abstract

A simple, mild and general method has been developed for the preparation of alkyl nitramines bearing a halogenoalkoxylic moiety. From these reactive halogen intermediates, a few azidoalkoxyl alkyl nitramines have been produced as energetic plasticizers. This simple protocol allows azidonitramino ether plasticizers to be obtained from available precursors in high yields, as it is safe and viable for large-scale operations. The resulting products have been fully characterized by spectral methods, and their impact sensitivity, thermal transformations and burning properties were determined, thus allowing complete comparison to the analogues including other combinations of structural units. Such characterization of these new plasticizers illustrates the extent to which the nature and position of the functional units can be used to tune the above properties of these nitramines. All azidonitramino ethers are liquid with excellent energetic performance and are promising candidates for new environmentally friendly energetic materials.

Indexed as

azideburning ratecombustiondialkyl etherenergetic plasticizerimpact sensitivitynitraminephase transitionsynthesisthermal decompositionvolatility

Identifiers

PMID36431845
PMCPMC9695530

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.