Evidence map›Paper›PMID 36431825›Full record

ArticleMolecules (Basel, Switzerland)2022

Coordination Polymers of Polyphenyl-Substituted Potassium Cyclopentadienides.

Pavel D Komarov, Kirill P Birin, Alexander A Vinogradov, Evgenia A Varaksina, Lada N Puntus, Konstantin A Lyssenko, Andrei V Churakov, Ilya E Nifant'ev, Mikhail E Minyaev, Dmitrii M Roitershtein

Abstract read
In one paragraph

Article in Molecules (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
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1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Pavel D KomarovA.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky Prospect, 119991 Moscow, Russia.ORCID 0000-0003-4181-5022
Kirill P BirinA.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 31 Leninsky Prospect, Building 4, 119071 Moscow, Russia.ORCID 0000-0001-6951-2440
Alexander A VinogradovA.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky Prospect, 119991 Moscow, Russia.ORCID 0000-0002-7113-4183
Evgenia A VaraksinaA.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky Prospect, 119991 Moscow, Russia.
Lada N PuntusA.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky Prospect, 119991 Moscow, Russia.
Konstantin A LyssenkoChemistry Department, M.V. Lomonosov Moscow State University, 1 Leninskie Gory Str., Building 3, 119991 Moscow, Russia.ORCID 0000-0002-3500-1287
Andrei V ChurakovN.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Prospect, 119991 Moscow, Russia.ORCID 0000-0003-3336-4022
Ilya E Nifant'evA.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky Prospect, 119991 Moscow, Russia.
Mikhail E MinyaevA.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky Prospect, 119991 Moscow, Russia.ORCID 0000-0002-4089-3697
Dmitrii M RoitershteinA.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky Prospect, 119991 Moscow, Russia.ORCID 0000-0003-0320-1775

Funding

Russian Science Foundation 22-13-00312
6 · The paper itself

Abstract

A series of potassium salts of di- and tri-arylsubstituted cyclopentadienes has been obtained by the metalation of the corresponding cyclopentadienes with benzylpotassium in THF media. Crystals of all compounds, afforded by recrystallization from THF/hexane, diglyme-THF/hexane and toluene/hexane mixtures, have been studied by X-ray diffraction. All studied potassium cyclopentadienides exhibit the luminescence at room temperature and overall quantum yield of photoluminescence for potassium salt of diarylsubstituted cyclopentadiene is 18%.

Indexed as

charge transfercoordination polymercrystal structurecyclopentadienyldiphenylcyclopentadieneluminescencepotassiumtriphenylcyclopentadiene

Identifiers

PMID36431825
PMCPMC9696914

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