Evidence map›Paper›PMID 36430186›Full record

ArticleInternational journal of molecular sciences2022

TBPEH-TBPB Initiate the Radical Addition of Benzaldehyde and Allyl Esters.

Binlong Sun, Xiaoyu Tian, Sen Yang, Yingying Wang, Yingying Shao, Xinhao Fu, Wenyuan Wang, Minting Tu, Yang Chen, Junhui Wu and 2 more

Open access · goldAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in International journal of molecular sciences, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact, top 89% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed, 0 citations in OpenAlex.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors at 1 institution in 1 country.

Binlong SunCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
Xiaoyu TianCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
Sen YangCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
Yingying WangCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
Yingying ShaoCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
Xinhao FuCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
Wenyuan WangCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
Minting TuCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
Yang ChenCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
Junhui WuCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
Changyuan WuCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
Chengxia TanCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.ORCID 0000-0003-1000-8578
Zhejiang University of Technology · CN

Funding

Siga Co. Ltd. R & D Program KYY-HX-20210049Wynca Group KYY-HX-20180412
6 · The paper itself

Abstract

Tert-butylperoxy-2-ethylhexanoate (TBPEH) and tert-butyl peroxybenzoate (TBPB) promote the radical acylation of allyl ester with benzaldehyde to synthesize new carbonyl-containing compounds under solvent-free and metal-free conditions. This reaction is compatible with electron-donating and halogen groups and has excellent atom utilization and chemical selectivity. Furthermore, the synthetic compounds can further apply to the preparation of lactone, piperidine, tetrazole and oxazole.

Indexed as

BenzaldehydesEstersBenzoatesPeroxidesbenzaldehydeBenzaldehydesBenzoatesEstersPeroxidestert-butyl peroxybenzoateallyl estermetal-freeolefin acylationradical additionTBPEH-TBPB

Identifiers

PMID36430186
PMCPMC9690988
OpenAlexW4308527768

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.