ArticleRSC advances2022
Bromide ion promoted practical synthesis of phosphinothioates of sulfinic acid derivatives and H-phosphine oxides.
Article in RSC advances, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Chemoselective Alkylating Esterification of Thiophosphinic Acids: An Experimental and Theoretical Study.ChemPlusChem · 2026Article
- Metal- and Solvent-Free Synthesis of Phosphinothioates, Phosphonothioates, Phosphorothioates, and Related Selenium Derivatives: An Efficient Green Protocol.Molecules (Basel, Switzerland) · 2025Article
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9 authors.
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Abstract
A feasible method for the synthesis of phosphinothioates from sulfinic acid derivatives and phosphine oxides is described. This reaction can be carried out in an open flask at room temperature and in an aqueous medium. The scope of the sulfinic acid derivatives is extensive, with a wide range of sulfinate esters, sulfinic acids, and sodium sulfinates compatible with these conditions, with good to excellent yields of phosphinothioates. In addition, a gram-scale synthesis with this reaction is achieved. A mechanism of this procedure was proposed.
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