Evidence map›Paper›PMID 36425494›Full record

ArticleChemical science2022

Ruthenium nanoparticles canopied by heptagon-containing saddle-shaped nanographenes as efficient aromatic hydrogenation catalysts.

Christian Cerezo-Navarrete, Arthur H G David, Adrián García-Zaragoza, Marcos D Codesal, Pascual Oña-Burgos, Iker Del Rosal, Romuald Poteau, Araceli G Campaña, Luis M Martínez-Prieto

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In one paragraph

Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Christian Cerezo-NavarreteITQ, Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas Av. de los Naranjos 46022 Valencia Spain luismiguel.martinez@csic.es.ORCID https://orcid.org/0000-0001-9537-0642
Arthur H G DavidDepartamento Química Orgánica, Universidad de Granada (UGR), C. U. Fuentenueva 18071 Granada Spain.
Adrián García-ZaragozaITQ, Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas Av. de los Naranjos 46022 Valencia Spain luismiguel.martinez@csic.es.ORCID https://orcid.org/0000-0001-5114-1063
Marcos D CodesalDepartamento Química Orgánica, Universidad de Granada (UGR), C. U. Fuentenueva 18071 Granada Spain.
Pascual Oña-BurgosITQ, Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas Av. de los Naranjos 46022 Valencia Spain luismiguel.martinez@csic.es.
Iker Del RosalLPCNO; Laboratoire de Physique et Chimie des Nano-Objets, INSA-CNRS (UMR 5215)-UPS, Institut National des Sciences Appliquées 135, Avenue de Rangueil F-31077 Toulouse France.ORCID https://orcid.org/0000-0001-6898-4550
Romuald PoteauLPCNO; Laboratoire de Physique et Chimie des Nano-Objets, INSA-CNRS (UMR 5215)-UPS, Institut National des Sciences Appliquées 135, Avenue de Rangueil F-31077 Toulouse France.ORCID https://orcid.org/0000-0003-4338-174X
Araceli G CampañaDepartamento Química Orgánica, Universidad de Granada (UGR), C. U. Fuentenueva 18071 Granada Spain.ORCID https://orcid.org/0000-0001-5483-5642
Luis M Martínez-PrietoITQ, Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas Av. de los Naranjos 46022 Valencia Spain luismiguel.martinez@csic.es.ORCID https://orcid.org/0000-0002-3401-4967

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The search for new ligands capable of modifying the metal nanoparticle (MNP) catalytic behavior is of increasing interest. Herein we present the first example of RuNPs stabilized with non-planar heptagon-containing saddle-shaped nanographenes (Ru@1 and Ru@2). The resemblance to graphene-supported MNPs makes these non-planar nanographene-stabilized RuNPs very attractive systems to further investigate graphene-metal interactions. A combined theoretical/experimental study allowed us to explore the coordination modes and dynamics of these nanographenes at the Ru surface. The curvature of these saddle-shaped nanographenes makes them efficient MNP stabilizers. The resulting RuNPs were found to be highly active catalysts for the hydrogenation of aromatics, including platform molecules derived from biomass (

Identifiers

PMID36425494
PMCPMC9667958

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.