Evidence map›Paper›PMID 36425484›Full record

ArticleChemical science2022

Ligand-free nickel catalyzed perfluoroalkylation of arenes and heteroarenes.

Shubham Deolka, Ramadoss Govindarajan, Serhii Vasylevskyi, Michael C Roy, Julia R Khusnutdinova, Eugene Khaskin

Abstract read
In one paragraph

Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Review
  2. Review
  3. Article
  4. Bi-Catalyzed Trifluoromethylation of C(spJournal of the American Chemical Society · 2023
    Article
  5. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Shubham DeolkaCoordination Chemistry and Catalysis Unit, Okinawa Institute of Science and Technology Graduate University 1919-1 Tancha, Onna-son 904-0495 Okinawa Japan eugene.khaskin@oist.jp.
Ramadoss GovindarajanCoordination Chemistry and Catalysis Unit, Okinawa Institute of Science and Technology Graduate University 1919-1 Tancha, Onna-son 904-0495 Okinawa Japan eugene.khaskin@oist.jp.
Serhii VasylevskyiCoordination Chemistry and Catalysis Unit, Okinawa Institute of Science and Technology Graduate University 1919-1 Tancha, Onna-son 904-0495 Okinawa Japan eugene.khaskin@oist.jp.ORCID https://orcid.org/0000-0001-6219-6051
Michael C RoyCoordination Chemistry and Catalysis Unit, Okinawa Institute of Science and Technology Graduate University 1919-1 Tancha, Onna-son 904-0495 Okinawa Japan eugene.khaskin@oist.jp.
Julia R KhusnutdinovaCoordination Chemistry and Catalysis Unit, Okinawa Institute of Science and Technology Graduate University 1919-1 Tancha, Onna-son 904-0495 Okinawa Japan eugene.khaskin@oist.jp.ORCID https://orcid.org/0000-0002-5911-4382
Eugene KhaskinCoordination Chemistry and Catalysis Unit, Okinawa Institute of Science and Technology Graduate University 1919-1 Tancha, Onna-son 904-0495 Okinawa Japan eugene.khaskin@oist.jp.ORCID https://orcid.org/0000-0003-1790-704X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We describe a "ligand-free" Ni-catalyzed perfluoroalkylation of heteroarenes to produce a diverse array of trfiluoromethyl, pentafluoroethyl and heptafluoropropyl adducts. Catalysis proceeds at room temperature

Identifiers

PMID36425484
PMCPMC9667918

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.