ArticleChemistry (Weinheim an der Bergstrasse, Germany)2023
Pushing Photochemistry into Water: Acceleration of the Di-π-Methane Rearrangement and the Paternó-Büchi Reaction "On-Water".
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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3 citing papers in PubMed.
- Diblock Copolypeptoid Micelles as Platform for Aqueous Photoredox Cyanation of Arenes.Journal of the American Chemical Society · 2025Article
- Valence Electronic Structure of Interfacial Phenol in Water Droplets.The journal of physical chemistry. A · 2024Article
- Pushing Photochemistry into Water: Acceleration of the Di-π-Methane Rearrangement and the Paternó-Büchi Reaction "On-Water".Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
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5 authors.
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Abstract
Two representative organic photoreactions, namely a bimolecular photocycloaddition and a monomolecular photorearrangement, are presented that are accelerated when the reaction is performed "on-water", that is, at the water-substrate interface with no solvation of the reaction components. According to the established models of ground-state reactions "on-water", the enhanced efficiency of the photoreactions is explained by hydrophobic effects (Paternó-Büchi reaction) or specific hydrogen bonding (di-π-methane rearrangement) at the water-substrate interface that decrease the energy of the respective transition state. These results point to the potential of this approach to conduct photoreactions more efficiently in an ecologically favorable medium.
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