Evidence map›Paper›PMID 36382288›Full record

ArticleChemical science2022

Chain transfer agents for the catalytic ring opening metathesis polymerization of norbornenes.

Indradip Mandal, Ankita Mandal, Md Atiur Rahman, Andreas F M Kilbinger

Open access · diamondAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
3.1field-weighted citation impact, top 8% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed, 28 citations in OpenAlex.

  1. Article
  2. Polymer-Metal-Organic Frameworks (polyMOFs) Based on Tailor-Made Poly(alkenamer)s.Chemistry of materials : a publication of the American Chemical Society · 2024
    Article
  3. Bottlebrush Networks: A Primer for Advanced Architectures.Angewandte Chemie (International ed. in English) · 2024
    Review
  4. Review
  5. Review
  6. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 1 institution in 1 country.

Indradip MandalDepartment of Chemistry, University of Fribourg Chemin du Musée 9 1700 Fribourg Switzerland andreas.kilbinger@unifr.ch.ORCID https://orcid.org/0000-0003-4552-7415
Ankita MandalDepartment of Chemistry, University of Fribourg Chemin du Musée 9 1700 Fribourg Switzerland andreas.kilbinger@unifr.ch.ORCID https://orcid.org/0000-0002-2743-3258
Md Atiur RahmanDepartment of Chemistry, University of Fribourg Chemin du Musée 9 1700 Fribourg Switzerland andreas.kilbinger@unifr.ch.
Andreas F M KilbingerDepartment of Chemistry, University of Fribourg Chemin du Musée 9 1700 Fribourg Switzerland andreas.kilbinger@unifr.ch.ORCID https://orcid.org/0000-0002-2929-7499
University of Fribourg · CH

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Here, we present a detailed study of the metathesis activity of conjugated 1,3 diene derivatives in ring opening metathesis polymerization (ROMP) using Grubbs' 3rd generation catalyst (G3). A comprehensive screening of those derivatives revealed that monosubstituted 1,3 dienes show similar reactivities towards G3-alkylidenes as norbornene derivatives. Therefore, they represent perfect candidates for chain transfer agents in a kinetically controlled catalytic ROMP. This unprecedented reactivity allowed us to catalytically synthesize mono-end-functional poly(norborneneimide)s on the gram scale. Much more complex architectures such as star-shaped polymers could also be synthesized catalytically for the very first time

Identifiers

PMID36382288
PMCPMC9629056
OpenAlexW4309244662

What OpenQuestion holds

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LicenceCC BY-NC
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.