Evidence map›Paper›PMID 36378626›Full record

ArticleJournal of the American Chemical Society2022

Metal-Ligand Role Reversal: Hydride-Transfer Catalysis by a Functional Phosphorus Ligand with a Spectator Metal.

Quinton J Bruch, Akira Tanushi, Peter Müller, Alexander T Radosevich

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Article
  2. CAngewandte Chemie (International ed. in English) · 2026
    Article
  3. Direct OJACS Au · 2025
    Article
  4. Article
  5. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Quinton J BruchDepartment of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States.ORCID 0000-0002-3653-1036
Akira TanushiDepartment of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States.ORCID 0000-0002-9461-5529
Peter MüllerDepartment of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States.ORCID 0000-0001-6530-3852
Alexander T RadosevichDepartment of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States.ORCID 0000-0002-5373-7343

Funding

Inverting Coupling Selectivity with Cooperative Metal-Ligand ConstructsR21GM134240 · NIGMS · MASSACHUSETTS INSTITUTE OF TECHNOLOGY · PI RADOSEVICH, ALEXANDER T · 2019 to 2020
$377k
Development of Nontrigonal Phosphorus Catalysts for Redox-Mediated Cross-Coupling TransformationsF32GM143865 · NIGMS · MASSACHUSETTS INSTITUTE OF TECHNOLOGY · PI BRUCH, QUINTON JAMES · 2021 to 2023
$144k
NIGMS NIH HHS F32 GM143865NIGMS NIH HHS R21 GM134240
6 · The paper itself

Abstract

Hydride transfer catalysis is shown to be enabled by the nonspectator reactivity of a transition metal-bound low-symmetry tricoordinate phosphorus ligand. Complex

Indexed as

PhosphorusTransition ElementsCatalysisLigandsMetalsLigandsMetalsPhosphorusTransition Elements

Identifiers

PMID36378626
PMCPMC9712262

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.