ArticleJournal of the American Chemical Society2022
Altering the Properties of Spiropyran Switches Using Coordination Cages with Different Symmetries.
Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Photoresponsive mesoporous silica nanocarriers for paraquat with substantially reduced acute toxicity and effective weed control.Pest management science · 2026Article
- Oxygen-Acceptor-Driven High Photochromic Contrast Solid-State Excited-State Intramolecular Proton Transfer Photoswitches.Angewandte Chemie (International ed. in English) · 2026Article
- Photoswitchable Merocyanine-Amphiphiles with Programmable Self-Assembly Times.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Harnessing Dynamic Supramolecular Interactions for Lanthanide Detection via Computational Pattern Recognition of Magnetic Resonance Fingerprints.Journal of the American Chemical Society · 2025Article
- Potential antibacterial effects and transcriptomic analysis of a novel reversible photoacid-based crystalline coordination polymer.Frontiers in microbiology · 2025Article
- Article
- Synthesis, Characterization, and Photochemistry of a GaInorganic chemistry · 2024Article
- Photoswitching the fluorescence of nanoparticles for advanced optical applications.Chemical science · 2024Review
- Solvation-Tuned Photoacid as a Stable Light-Driven pH Switch for COChemistry of materials : a publication of the American Chemical Society · 2024Article
- Photoswitchable coordination cages.Nature chemistry · 2024Review
- Breaking the photoswitch speed limit.Nature communications · 2023Article
- Guest Encapsulation Alters the Thermodynamic Landscape of a Coordination Host.Journal of the American Chemical Society · 2023Article
- NMR exchange dynamics studies of metal-capped cyclodextrins reveal multiple populations of host-guest complexes in solution.Chemical science · 2023Article
- Ligand-protected nanocluster-mediated photoswitchable fluorescent nanoprobes towards dual-color cellular imaging.Chemical science · 2023Article
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Molecular confinement effects can profoundly alter the physicochemical properties of the confined species. A plethora of organic molecules were encapsulated within the cavities of supramolecular hosts, and the impact of the cavity size and polarity was widely investigated. However, the extent to which the properties of the confined guests can be affected by the symmetry of the cage─which dictates the shape of the cavity─remains to be understood. Here we show that cage symmetry has a dramatic effect on the equilibrium between two isomers of the encapsulated spiropyran guests. Working with two Pd-based coordination cages featuring similarly sized but differently shaped hydrophobic cavities, we found a highly selective stabilization of the isomer whose shape matches that of the cavity of the cage. A
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Registered trials
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