ArticleAngewandte Chemie (International ed. in English)2023
Synthesis and Degradation of Vinyl Polymers with Evenly Distributed Thioacetal Bonds in Main Chains: Cationic DT Copolymerization of Vinyl Ethers and Cyclic Thioacetals.
Article in Angewandte Chemie (International ed. in English), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed, 36 citations in OpenAlex.
- Beyond Traditional RAFT Polymerization: Emerging Strategies and Future Perspectives; A Third Update.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Review
- Synthesis of Degradable Polystyrene and Its Derivative with In-Chain Thioester via Radical and Cationic Copolymerizations with a Seven-Membered Benzene-Fused Thionolactone.Polymer science & technology (Washington, D.C.) · 2025Article
- On-demand, readily degradable Poly-2,3-dihydrofuran enabled by anion-binding catalytic copolymerization.Nature communications · 2025Article
- Cationic polymerization of vinyl ethers using trifluoromethyl sulfonate/solvent/ligand to access well-controlled poly(vinyl ether)s.Chemical science · 2025Article
- An Expedient Route to Bio-Based Polyacrylate Alternatives with Inherent Post-Chemical Modification and Degradation Capabilities by Organic Catalysis for Polymerization of Muconate Esters.Angewandte Chemie (International ed. in English) · 2024Article
- RAFT step-growth polymerizationChemical science · 2024Article
- Selective poly(vinyl ether) upcyclingChemical science · 2024Article
- Direct Radical Copolymerizations of Thioamides To Generate Vinyl Polymers with Degradable Thioether Bonds in the Backbones.Journal of the American Chemical Society · 2023Article
- Synthesis and Degradation of Vinyl Polymers with Evenly Distributed Thioacetal Bonds in Main Chains: Cationic DT Copolymerization of Vinyl Ethers and Cyclic Thioacetals.Angewandte Chemie (International ed. in English) · 2023Article
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Authors and funding
4 authors at 2 institutions in 1 country.
Funding
Abstract
We report a novel method to synthesize degradable poly(vinyl ether)s with cleavable thioacetal bonds periodically arranged in the main chains using controlled cationic copolymerization of vinyl ethers with a 7-membered cyclic thioacetal (7-CTA) via degenerative chain transfer (DT) to the internal thioacetal bonds. The thioacetal bonds, which are introduced into the main chain by cationic ring-opening copolymerization of 7-CTA with vinyl ethers, serve as in-chain dormant species to allow homogeneous propagation of vinyl ethers for all internal segments to afford copolymers with controlled overall and segmental molecular weights. The obtained polymers can be degraded into low- and controlled-molecular-weight polymers with narrow molecular weight distributions via hydrolysis. Various vinyl ethers with hydrophobic, hydrophilic, and functional pendants are available. Finally, one-pot synthesis of multiblock copolymers and their degradation into diblock copolymers are also achieved.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.