The Mechanical Properties Prediction of Poly [(3-hydroxybutyrate)-co-(3-hydroxyvalerate)] (PHBV) Biocomposites on a Chosen Example.

This paper aims to experimentally determine the properties of the poly [(3-hydroxybutyrate)-co-(3-hydroxyvalerate)]-(PHBV)-30% hemp fiber biocomposite, which is important in terms of numerical simulations of product manufacturing, and to evaluate the mechanical properties by means of micromechanical modeling. The biocomposite was manufactured using a single-screw extruder. Specimens for testing were produced by applying the injection molding technology. Utilizing the simulation results of the plastic flow, carried out by the Moldflow Insight 2016 commercial software and the results of experimental tests, the forecasts of selected composite mechanical properties were performed by means of both numerical and analytical homogenization methods. For this purpose, the Digimat software was applied. The necessary experimental data to perform the calculations for the polymer matrix, fibers, and the biocomposite were obtained by rheological and thermal studies as well as elementary mechanical tests. In the paper, the method of determining selected properties of the biocomposite and the method of forecasting its other properties are discussed. It shows the dependence of the predicted, selected properties of the biocomposite on the filler geometry assumed in the calculations and the homogenization method adopted for the calculations. The results of the work allow for the prediction of properties of the PHBV biocomposites-hemp fiber for any amount of filler used. Moreover, the results allow for the estimation of the usefulness of homogenization methods for the prediction of properties of the PHBV-hemp fiber biocomposites. Furthermore, it was found that for the developed and tested biocomposites, the most effective possibility of mechanical properties prediction is using the Mori-Tanaka homogenization model, which unfortunately has some limitations.