Evidence map›Paper›PMID 36362367›Full record

ArticleInternational journal of molecular sciences2022

Reaction of Corroles with Sarcosine and Paraformaldehyde: A New Facet of Corrole Chemistry.

Joana F B Barata, Paula S S Lacerda, Maria Graça P M S Neves, José A S Cavaleiro, Catarina I V Ramos, Augusto C Tomé, Paulo E Abreu, Alberto A C C Pais

Abstract read
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In one paragraph

Article in International journal of molecular sciences, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0citing papers in PubMed
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1 · What the graph read from it

What it found

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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

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Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Joana F B BarataCESAM, University of Aveiro, 3810-193 Aveiro, Portugal.ORCID 0000-0002-0794-144X
Paula S S LacerdaCESAM, University of Aveiro, 3810-193 Aveiro, Portugal.ORCID 0000-0002-9003-0574
Maria Graça P M S NevesLAQV-REQUIMTE, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal.ORCID 0000-0002-7953-8166
José A S CavaleiroLAQV-REQUIMTE, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal.ORCID 0000-0001-5495-5126
Catarina I V RamosLAQV-REQUIMTE, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal.ORCID 0000-0002-0200-2005
Augusto C ToméLAQV-REQUIMTE, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal.ORCID 0000-0003-4331-714X
Paulo E AbreuDepartment of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal.ORCID 0000-0003-2393-0203
Alberto A C C PaisDepartment of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal.

Funding

Fundação para a Ciência e Tecnologia CESAM (UIDP/50017/2020 + UIDB/50017/2020 + LA/P/0094/2020Fundação para a Ciência e Tecnologia C. I. V. R. thanks for her contract 047-88-ARH/2018.Fundação para a Ciência e Tecnologia LAQV-REQUIMTE (UIDB/50006/2020)Fundação para a Ciência e Tecnologia P.S. S. L. thanks POCI-01-0145-FEDER-031523Fundação para a Ciência e TEcnologia POCI-01-0145-FEDER-031523Portuguese NMR Network Infrastructure Project No. 022161
6 · The paper itself

Abstract

Details on the unexpected formation of two new (dimethylamino)methyl corrole isomers from the reaction of 5,10,15-tris(pentafluorophenyl)corrolatogallium(III) with sarcosine and paraformaldehyde are presented. Semi-empirical calculations on possible mechanism pathways seem to indicate that the new compounds are probably formed through a Mannich-type reaction. The extension of the protocol to the free-base 5,10,15-tris(pentafluorophenyl)corrole afforded an unexpected new seven-membered ring corrole derivative, confirming the peculiar behavior of corroles towards known reactions when compared to the well-behaved porphyrin counterparts.

Indexed as

PorphyrinsSarcosineFormaldehydeIsomerismPolymerscorroleFormaldehydeparaformPolymersPorphyrinsSarcosinecorroleenthalpyMannich-type reactionmetallocorrolePM7 semi-empirical calculations

Identifiers

PMID36362367
PMCPMC9658120

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.