Evidence map›Paper›PMID 36350079›Full record

ArticleOrganic letters2022

Dynamic Hydroxyl-Yne Reaction with Phenols.

Tanausú Santos, Yaiza Pérez-Pérez, David S Rivero, Raquel Diana-Rivero, Fernando García-Tellado, David Tejedor, Romen Carrillo

Abstract read
In one paragraph

Article in Organic letters, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Tanausú SantosInstituto Universitario de Bio-Orgánica Antonio González (IUBO), Universidad de La Laguna, P.O. Box 456, 38206 La Laguna, Tenerife, Spain.
Yaiza Pérez-PérezInstituto de Productos Naturales y Agrobiología (IPNA-CSIC), Avda. Astrofísico Fco. Sánchez 3, 38206 La Laguna, Spain.
David S RiveroInstituto de Productos Naturales y Agrobiología (IPNA-CSIC), Avda. Astrofísico Fco. Sánchez 3, 38206 La Laguna, Spain.
Raquel Diana-RiveroInstituto de Productos Naturales y Agrobiología (IPNA-CSIC), Avda. Astrofísico Fco. Sánchez 3, 38206 La Laguna, Spain.
Fernando García-TelladoInstituto de Productos Naturales y Agrobiología (IPNA-CSIC), Avda. Astrofísico Fco. Sánchez 3, 38206 La Laguna, Spain.ORCID 0000-0001-6470-6289
David TejedorInstituto de Productos Naturales y Agrobiología (IPNA-CSIC), Avda. Astrofísico Fco. Sánchez 3, 38206 La Laguna, Spain.
Romen CarrilloInstituto de Productos Naturales y Agrobiología (IPNA-CSIC), Avda. Astrofísico Fco. Sánchez 3, 38206 La Laguna, Spain.ORCID 0000-0002-7078-300X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Dynamic Covalent Chemistry (DCvC) has gained increasing importance in supramolecular chemistry and materials science. Herein we prove the dynamic nature of the exchange between phenols and vinyl ethers. Exchange is fast at room temperature and under mild conditions. The equilibrium constants and the electronic effect of the phenol substituents were calculated. This novel incorporation to the DCvC toolbox could be quite useful, and as a proof it was used for the synthesis of a responsive molecular cage.

Identifiers

PMID36350079
PMCPMC10443044

What OpenQuestion holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.