ArticleJournal of the American Chemical Society2022
Oxidation by Reduction: Efficient and Selective Oxidation of Alcohols by the Electrocatalytic Reduction of Peroxydisulfate.
Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed, 57 citations in OpenAlex.
- Copper Nanoparticle Confinement in P‑Doped Carbon Nitride Templates Enables Efficient Peroxymonosulfate Activation for Alcohol Oxidation.ACS omega · 2026Article
- Article
- Stoichiometry-driven electronic heterogeneity in covalent organic frameworks for coupled HNature communications · 2026Article
- Evolution of Methods for the Oxidation of Primary Alcohols to Carboxylic Acids: From Metal Oxides to Biocatalysis.JACS Au · 2026Review
- [Research progress in the application of molecular imprinting technology in catalysis].Se pu = Chinese journal of chromatography · 2026Article
- Computational Electrosynthesis: A Perspective on Mechanistic Questions, Methodological Approaches, and Elucidating the Role of the Electrical Double Layer.The journal of physical chemistry. C, Nanomaterials and interfaces · 2025Review
- Electroprecipitating the Sulfate Radical Anion Amplifies Electrochemiluminescence in Space and Time.Journal of the American Chemical Society · 2024Article
- Electroreductive deuteroarylation of alkenes enabled by an organo-mediator.Chemical science · 2024Article
- Advanced Electroanalysis for Electrosynthesis.ACS organic & inorganic Au · 2024Review
- Catalytic Reduction of Cyanide to Ammonia and Methane at a Mononuclear Fe Site.Journal of the American Chemical Society · 2024Article
Corrections and comments
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Authors and funding
6 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Alcohol oxidation is an important class of reaction that is traditionally performed under harsh conditions and most often requires the use of organometallic compounds or transition metal complexes as catalysts. Here, we introduce a new electrochemical synthetic method, referred to as reductive oxidation, in which alcohol oxidation is initiated by the redox-mediated electrocatalytic reduction of peroxydisulfate to generate the highly oxidizing sulfate radical anion. Thus, and counter-intuitively, alcohol oxidation occurs as a result of an electrochemical reduction reaction. This approach provides a selective synthetic route for the oxidation of alcohols carried out under mild conditions to aldehydes, ketones, and carboxylic acids with up to 99% conversion yields. First-principles density functional theory calculations, ab initio molecular dynamics simulations, cyclic voltammetry, and finite difference simulations are presented that support and provide additional insights into the S
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.