Evidence map›Paper›PMID 36330879›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2023

How Bases Catalyze Diels-Alder Reactions.

Song Yu, Eveline H Tiekink, Pascal Vermeeren, F Matthias Bickelhaupt, Trevor A Hamlin

Open access · hybridAbstract read
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
1.0field-weighted citation impact, top 28% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed, 9 citations in OpenAlex.

  1. Insights into Tetrazine-Benzene Cycloadditions.The journal of physical chemistry. A · 2026
    Article
  2. Fe-doped carbon dots: a novel fluorescent nanoprobe for cellular hypochlorous acid imaging.Analytical sciences : the international journal of the Japan Society for Analytical Chemistry · 2024
    Article
  3. How Bases Catalyze Diels-Alder Reactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors at 1 institution in 2 countries.

Song YuDepartment of Theoretical Chemistry, Amsterdam Institute of Molecular and Life Sciences (AIMMS), Amsterdam Center for Multiscale Modeling (ACMM) Vrije Universiteit Amsterdam, De Boelelaan 1083, 1081 HV, Amsterdam, (TheNetherlands.ORCID http://orcid.org/0000-0001-5693-7773
Eveline H TiekinkDepartment of Theoretical Chemistry, Amsterdam Institute of Molecular and Life Sciences (AIMMS), Amsterdam Center for Multiscale Modeling (ACMM) Vrije Universiteit Amsterdam, De Boelelaan 1083, 1081 HV, Amsterdam, (TheNetherlands.ORCID http://orcid.org/0000-0003-4155-4889
Pascal VermeerenDepartment of Theoretical Chemistry, Amsterdam Institute of Molecular and Life Sciences (AIMMS), Amsterdam Center for Multiscale Modeling (ACMM) Vrije Universiteit Amsterdam, De Boelelaan 1083, 1081 HV, Amsterdam, (TheNetherlands.ORCID http://orcid.org/0000-0002-2100-6837
F Matthias BickelhauptDepartment of Theoretical Chemistry, Amsterdam Institute of Molecular and Life Sciences (AIMMS), Amsterdam Center for Multiscale Modeling (ACMM) Vrije Universiteit Amsterdam, De Boelelaan 1083, 1081 HV, Amsterdam, (TheNetherlands.ORCID http://orcid.org/0000-0003-4655-7747
Trevor A HamlinDepartment of Theoretical Chemistry, Amsterdam Institute of Molecular and Life Sciences (AIMMS), Amsterdam Center for Multiscale Modeling (ACMM) Vrije Universiteit Amsterdam, De Boelelaan 1083, 1081 HV, Amsterdam, (TheNetherlands.ORCID http://orcid.org/0000-0002-5128-1004
Radboud University Nijmegen · NL

Funding

Netherlands Organization for Scientific Research (NWO)
6 · The paper itself

Abstract

We have quantum chemically studied the base-catalyzed Diels-Alder (DA) reaction between 3-hydroxy-2-pyrone and N-methylmaleimide using dispersion-corrected density functional theory. The uncatalyzed reaction is slow and is preceded by the extrusion of CO

Indexed as

activation strain modelbase catalysisdensity functional calculationsDiels-Alder reactionsreactivity

Identifiers

PMID36330879
PMCPMC10108159
OpenAlexW4308187991

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.