ArticleChemical science2022
Alkoxysulfonyl radical species: acquisition and transformation towards sulfonate esters through electrochemistry.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Electrochemical Three-Component Synthesis of Vinyl Sulfonamides via Decarboxylative Sulfonylation of Cinnamic Acids.ChemSusChem · 2026Article
- Drawing from the Old-The First Ever Sultone as Electrolyte Additive in High-Voltage NMC811 || AG+SiOx Multilayer Pouch Cells.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Electrochemical Three-component Synthesis of Alkenesulfonates from Cinnamic Acids, SOChemSusChem · 2025Article
- Radical-Mediated Trifunctionalization Reactions.Molecules (Basel, Switzerland) · 2024Review
- An efficient and mild oxidative approach from thiols to sulfonyl derivatives with DMSO/HBr.Chemical science · 2023Article
Corrections and comments
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Sulfonyl radical mediated processes have been considered as a powerful strategy for the construction of sulfonyl compounds. However, an efficient and high atom-economical radical approach to the synthesis of sulfonate esters is still rare, owing to the limited tactics to achieve alkoxysulfonyl radicals. Herein, an electrochemical anodic oxidation of inorganic sulfites with alcohols is developed to afford alkoxysulfonyl radical species, which are utilized in subsequent alkene difunctionalization to provide various sulfonate esters. This transformation features excellent chemoselectivity and broad functional group tolerance. This new discovery presents the potential prospect for the construction of sulfonate esters, and enriches the electrochemical reaction type.
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Registered trials
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