Evidence map›Paper›PMID 36320913›Full record

ArticleChemical science2022

Photochemistry of pyruvic acid is governed by photo-induced intermolecular electron transfer through hydrogen bonds.

Jennifer S Lewis, Adam P Gaunt, Arnaud Comment

Abstract read
In one paragraph

Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed.

  1. Article
  2. Photochemistry of Sodium Pyruvate Clusters.The journal of physical chemistry. A · 2026
    Article
  3. Across-cities transportableNature communications · 2026
    Article
  4. Article
  5. The Singlet-Triplet Gap of Pyruvic Acid.Journal of the American Chemical Society · 2025
    Article
  6. Article
  7. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Jennifer S LewisCancer Research UK Cambridge Institute, University of Cambridge Robinson Way Cambridge CB2 0RE UK arnaud.comment@ge.com.
Adam P GauntCancer Research UK Cambridge Institute, University of Cambridge Robinson Way Cambridge CB2 0RE UK arnaud.comment@ge.com.
Arnaud CommentCancer Research UK Cambridge Institute, University of Cambridge Robinson Way Cambridge CB2 0RE UK arnaud.comment@ge.com.ORCID https://orcid.org/0000-0002-8484-3448

Funding

European Research Council 682574
6 · The paper itself

Abstract

Despite more than 85 years of research, the mechanism behind the photodecarboxylation of pyruvic acid remains elusive. Most studies focused on the gas and liquid phase of diluted solutions of pyruvic acid to understand the impact of sun light on the degradation of this molecule in the atmosphere. By analyzing concentrated supercooled solutions at 77 K, we demonstrate that instead of decarboxylating, the pyruvic acid molecule plays the role of electron donor and transfers an electron to an acceptor molecule that subsequently degrades to form CO

Identifiers

PMID36320913
PMCPMC9580485

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.