ArticleChemical science2022
Excimer evolution hampers symmetry-broken charge-separated states.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Solvent-Mediated Phase Propagation Governs Excitonic Heterogeneity in Chiral Fibrils.ACS central science · 2026Article
- Excimer-mediated multiexciton generation in covalently linked cross foldamers of thiophene-fused perylene bisimides.Chemical science · 2026Article
- Controlling triplet-pair formation in acene-bridged trimers through locally excited-charge-transfer state mixing.Chemical science · 2026Article
- Conformational switching modulates excited-state pathways in a cofacial perylene dimer.Chemical science · 2026Article
- Tuning the Inter-Chromophore Electronic Coupling in Perylene Diimide Dimers with Rigid Covalent Linkers.Molecules (Basel, Switzerland) · 2025Article
- Symmetry-Breaking Charge-Separation in a Subphthalocyanine Dimer Resolved by Two-Dimensional Electronic Spectroscopy.The journal of physical chemistry. C, Nanomaterials and interfaces · 2025Article
- An elegant approach for the synthesis of multisubstituted imidazoleRSC advances · 2024Article
- Sculpting photoproducts with DNA origami.Chem · 2024Article
- Ultrafast symmetry-breaking charge separation in Perylenemonoimide-embedded multichromophores: impact of regioisomerism.Chemical science · 2024Article
- Competitive Charge Separation Pathways in a Flexible Molecular Folda-Dimer.The journal of physical chemistry. B · 2024Article
- High-Efficiency Photoinduced Charge Separation in Fe(III)carbene Thin Films.Journal of the American Chemical Society · 2023Article
- Anomalous deep-red luminescence of perylene black analogues with strong π-π interactions.Nature communications · 2023Article
- From symmetry breaking to symmetry swapping: is Kasha's rule violated in multibranched phenyleneethynylenes?Chemical science · 2023Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Achieving long-lived symmetry-broken charge-separated states in chromophoric assemblies is quintessential for enhanced performance of artificial photosynthetic mimics. However, the occurrence of energy trap states hinders exciton and charge transport across photovoltaic devices, diminishing power conversion efficiency. Herein, we demonstrate unprecedented excimer formation in the relaxed excited-state geometry of bichromophoric systems impeding the lifetime of symmetry-broken charge-separated states. Core-annulated perylenediimide dimers (SC-SPDI
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