Evidence map›Paper›PMID 36320395›Full record

ArticleChemical science2022

Open-air green-light-driven ATRP enabled by dual photoredox/copper catalysis.

Grzegorz Szczepaniak, Jaepil Jeong, Kriti Kapil, Sajjad Dadashi-Silab, Saigopalakrishna S Yerneni, Paulina Ratajczyk, Sushil Lathwal, Dirk J Schild, Subha R Das, Krzysztof Matyjaszewski

Abstract read
In one paragraph

Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 35 papers.

0numbers the graph read from it
0cells of the map it votes in
35citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

35 citing papers in PubMed.

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  18. ATRP with ppb Concentrations of Photocatalysts.Journal of the American Chemical Society · 2024
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Grzegorz SzczepaniakDepartment of Chemistry, Carnegie Mellon University Pittsburgh Pennsylvania 15213 USA gszczepa@andrew.cmu.edu matyjaszewski@cmu.edu.ORCID https://orcid.org/0000-0002-0355-9542
Jaepil JeongDepartment of Chemistry, Carnegie Mellon University Pittsburgh Pennsylvania 15213 USA gszczepa@andrew.cmu.edu matyjaszewski@cmu.edu.ORCID https://orcid.org/0000-0002-1453-0964
Kriti KapilDepartment of Chemistry, Carnegie Mellon University Pittsburgh Pennsylvania 15213 USA gszczepa@andrew.cmu.edu matyjaszewski@cmu.edu.
Sajjad Dadashi-SilabDepartment of Chemistry, Carnegie Mellon University Pittsburgh Pennsylvania 15213 USA gszczepa@andrew.cmu.edu matyjaszewski@cmu.edu.ORCID https://orcid.org/0000-0002-4285-5846
Saigopalakrishna S YerneniDepartment of Biomedical Engineering, Carnegie Mellon University Pittsburgh Pennsylvania 15213 USA.
Paulina RatajczykDepartment of Chemistry, Carnegie Mellon University Pittsburgh Pennsylvania 15213 USA gszczepa@andrew.cmu.edu matyjaszewski@cmu.edu.ORCID https://orcid.org/0000-0002-3437-2852
Sushil LathwalDepartment of Chemistry, Carnegie Mellon University Pittsburgh Pennsylvania 15213 USA gszczepa@andrew.cmu.edu matyjaszewski@cmu.edu.
Dirk J SchildDepartment of Chemistry, Carnegie Mellon University Pittsburgh Pennsylvania 15213 USA gszczepa@andrew.cmu.edu matyjaszewski@cmu.edu.ORCID https://orcid.org/0000-0003-0179-6023
Subha R DasDepartment of Chemistry, Carnegie Mellon University Pittsburgh Pennsylvania 15213 USA gszczepa@andrew.cmu.edu matyjaszewski@cmu.edu.ORCID https://orcid.org/0000-0002-5353-0422
Krzysztof MatyjaszewskiDepartment of Chemistry, Carnegie Mellon University Pittsburgh Pennsylvania 15213 USA gszczepa@andrew.cmu.edu matyjaszewski@cmu.edu.ORCID https://orcid.org/0000-0003-1960-3402

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Photoinduced atom transfer radical polymerization (photo-ATRP) has risen to the forefront of modern polymer chemistry as a powerful tool giving access to well-defined materials with complex architecture. However, most photo-ATRP systems can only generate radicals under biocidal UV light and are oxygen-sensitive, hindering their practical use in the synthesis of polymer biohybrids. Herein, inspired by the photoinduced electron transfer-reversible addition-fragmentation chain transfer (PET-RAFT) polymerization, we demonstrate a dual photoredox/copper catalysis that allows open-air ATRP under green light irradiation. Eosin Y was used as an organic photoredox catalyst (PC) in combination with a copper complex (X-Cu

Identifiers

PMID36320395
PMCPMC9557244

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.