Evidence map›Paper›PMID 36315420›Full record

ArticleAngewandte Chemie (International ed. in English)2023

Rhodium Single-Atom Catalyst Design through Oxide Support Modulation for Selective Gas-Phase Ethylene Hydroformylation.

Marcos G Farpón, Wilson Henao, Philipp N Plessow, Eva Andrés, Raúl Arenal, Carlo Marini, Giovanni Agostini, Felix Studt, Gonzalo Prieto

Open access · hybridAbstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.

0numbers the graph read from it
0cells of the map it votes in
14citing papers in PubMed
4.8field-weighted citation impact, top 3% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

14 citing papers in PubMed, 67 citations in OpenAlex.

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  9. A Multitechnique Study of CThe journal of physical chemistry. C, Nanomaterials and interfaces · 2024
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  13. A Multitechnique Study of CThe journal of physical chemistry. C, Nanomaterials and interfaces · 2023
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors at 4 institutions in 2 countries.

Marcos G FarpónITQ Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas (UPV-CSIC), Av. Los Naranjos s/n, 46022, Valencia, Spain.
Wilson HenaoITQ Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas (UPV-CSIC), Av. Los Naranjos s/n, 46022, Valencia, Spain.
Philipp N PlessowInstitute of Catalysis Research and Technology (IKFT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz Platz 1, 76344, Eggenstein-Leopoldshafen, Germany.ORCID http://orcid.org/0000-0001-9913-4049
Eva AndrésITQ Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas (UPV-CSIC), Av. Los Naranjos s/n, 46022, Valencia, Spain.
Raúl ArenalLaboratorio de Microscopias Avanzadas (LMA), Universidad de Zaragoza, Mariano Esquillor s/n, 50018, Zaragoza, Spain.ORCID http://orcid.org/0000-0002-2071-9093
Carlo MariniALBA Synchrotron Light Source, Carrer de la Llum 2-26, Cerdanyola del Vallès, Barcelona, Spain.
Giovanni AgostiniALBA Synchrotron Light Source, Carrer de la Llum 2-26, Cerdanyola del Vallès, Barcelona, Spain.ORCID http://orcid.org/0000-0003-1508-3809
Felix StudtInstitute of Catalysis Research and Technology (IKFT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz Platz 1, 76344, Eggenstein-Leopoldshafen, Germany.ORCID http://orcid.org/0000-0001-6841-4232
Gonzalo PrietoITQ Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas (UPV-CSIC), Av. Los Naranjos s/n, 46022, Valencia, Spain.ORCID http://orcid.org/0000-0002-0956-3040
Consejo Superior de Investigaciones Científicas · ESALBA Synchrotron (Spain) · ESKarlsruhe Institute of Technology · DEUniversidad de Zaragoza · ES

Funding

Gobierno de Aragón DGA E13-20RH2020 European Research Council 864195Helmholtz-GemeinschaftHorizon 2020 Framework Programme 823717Ministerio de Ciencia e Innovación PID2019-104739GB-100/AEI/10.13039/501100011033Ministerio de Ciencia, Innovación y Universidades RTI2018-096399-A-I00Ministerio de educación de España FPU17/04701Ministerio de Educación de España FPU17/04751Ministerium für Wissenschaft, Forschung und Kunst Baden-Württemberg RV bw17D011Spanish National Plan for Scientific and Technical Research and Innovation PRE2019-087571
6 · The paper itself

Abstract

A frontier challenge in single-atom (SA) catalysis is the design of fully inorganic sites capable of emulating the high reaction selectivity traditionally exclusive of organometallic counterparts in homogeneous catalysis. Modulating the direct coordination environment in SA sites, via the exploitation of the oxide support's surface chemistry, stands as a powerful albeit underexplored strategy. We report that isolated Rh atoms stabilized on oxygen-defective SnO

Indexed as

DFTOlefin ValorizationOxygen VacanciesSingle-Atom-CatalystsX-Ray Absorption Spectroscopy

Identifiers

PMID36315420
PMCPMC10099584
OpenAlexW4307697554

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.