Evidence map›Paper›PMID 36302695›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022

Influence of Pore Size in Benzoin Condensation of Furfural Using Heterogenized Benzimidazole Organocatalysts.

Ivana Miletto, Marta Meazza, Geo Paul, Maurizio Cossi, Enrica Gianotti, Leonardo Marchese, Ramon Rios, Marc Pera-Titus, Robert Raja

Abstract read
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Ivana MilettoDepartment of Pharmaceutical Sciences, Università del Piemonte Orientale, Largo Donegani 2/3, 28100, Novara, Italy.
Marta MeazzaSchool of Chemistry, University of Southampton, Highfield campus, Southampton, SO171BJ, UK.
Geo PaulDepartment of Science and Technological Innovation, Università del Piemonte Orientale, V. T. Michel 11, 15100, Alessandria, Italy.
Maurizio CossiDepartment of Science and Technological Innovation, Università del Piemonte Orientale, V. T. Michel 11, 15100, Alessandria, Italy.
Enrica GianottiDepartment for the Sustainable Development and Ecological Transition, Università del Piemonte Orientale, Piazza Sant'Eusebio 5, 13100, Vercelli, Italy.
Leonardo MarcheseDepartment of Science and Technological Innovation, Università del Piemonte Orientale, V. T. Michel 11, 15100, Alessandria, Italy.
Ramon RiosSchool of Chemistry, University of Southampton, Highfield campus, Southampton, SO171BJ, UK.
Marc Pera-TitusCardiff Catalysis Institute, School of Chemistry, Main Building, Cardiff University, Park Place, Cardiff, CF10 3AT, UK.ORCID http://orcid.org/0000-0001-7335-1424
Robert RajaSchool of Chemistry, University of Southampton, Highfield campus, Southampton, SO171BJ, UK.

Funding

Horizon 2020 Framework Programme 720783
6 · The paper itself

Abstract

A designed N-heterocyclic carbene (NHC) catalyst was covalently anchored on a range of mesoporous and hierarchical supports, to study the influence of pore size in the benzoin condensation of furfural. The structural and spectroscopic characteristics of the anchored catalysts were investigated, also with the help of molecular dynamics simulations, in order to rationalize the degree of stability and recyclability of the heterogenized organocatalysts. Quantitative yields (99 %) and complete recyclability were maintained after several cycles, vindicating the design rationale.

Indexed as

BenzoinFuraldehydeBenzimidazolesCatalysisMolecular Dynamics SimulationBenzimidazolesBenzoinFuraldehydebenzoin condensationfurfural transformationheterogeneous catalysisN-heterocyclic carbene based catalystsorganic-inorganic hybrid catalyst

Identifiers

PMID36302695
PMCPMC10108080

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.