Evidence map›Paper›PMID 36276031›Full record

ArticleRSC advances2022

Copper(ii) complexes with 2-ethylpyridine and related hydroxyl pyridine derivatives: structural, spectroscopic, magnetic and anticancer

Magdalena Malik, Anna Świtlicka, Alina Bieńko, Urszula K Komarnicka, Dariusz C Bieńko, Sandra Kozieł, Agnieszka Kyzioł, Tomasz Mazur, Barbara Machura

Open access · goldAbstract read
In one paragraph

Article in RSC advances, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
2.6field-weighted citation impact, top 8% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed, 29 citations in OpenAlex.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors at 4 institutions in 1 country.

Magdalena MalikFaculty of Chemistry, Wroclaw University of Science and Technology Wybrzeże Wyspiańskiego 27 50-370 Wrocław Poland magdalena.malik@pwr.edu.pl.ORCID https://orcid.org/0000-0002-4795-9687
Anna ŚwitlickaDepartment of Crystallography, Institute of Chemistry, University of Silesia Szkolna 9 40-006 Katowice Poland.ORCID https://orcid.org/0000-0001-8192-5619
Alina BieńkoFaculty of Chemistry, University of Wroclaw F. Joliot-Curie 14 50-383 Wrocław Poland.ORCID https://orcid.org/0000-0002-2714-3197
Urszula K KomarnickaFaculty of Chemistry, University of Wroclaw F. Joliot-Curie 14 50-383 Wrocław Poland.ORCID https://orcid.org/0000-0001-5250-9229
Dariusz C BieńkoFaculty of Chemistry, Wroclaw University of Science and Technology Wybrzeże Wyspiańskiego 27 50-370 Wrocław Poland magdalena.malik@pwr.edu.pl.ORCID https://orcid.org/0000-0002-8717-7065
Sandra KoziełFaculty of Chemistry, University of Wroclaw F. Joliot-Curie 14 50-383 Wrocław Poland.ORCID https://orcid.org/0000-0002-4970-9235
Agnieszka KyziołFaculty of Chemistry, Jagiellonian University Gronostajowa 2 30-387 Kraków Poland.ORCID https://orcid.org/0000-0002-5563-4508
Tomasz MazurFaculty of Chemistry, Wroclaw University of Science and Technology Wybrzeże Wyspiańskiego 27 50-370 Wrocław Poland magdalena.malik@pwr.edu.pl.
Barbara MachuraDepartment of Crystallography, Institute of Chemistry, University of Silesia Szkolna 9 40-006 Katowice Poland.ORCID https://orcid.org/0000-0001-7688-6491
University of Wrocław · PLWrocław University of Science and Technology · PLUniversity of Silesia in Katowice · PLJagiellonian University · PL

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Copper(ii) complexes with 2-ethylpyridine (1 and 2), 2-(hydroxyethyl)pyridine (3) and 2-(hydroxymethyl)pyridine (4) have been synthesized and characterized. All inorganic compounds have been studied by X-ray diffraction, thermogravimetry, vibrational and EPR spectroscopy as well as theoretical methods. The geometry of the complexes 1, 3 and 4 adopts nearly perfect geometry close to square planar (1, 4) or square pyramid (3) stereochemistry, respectively. The distortion of five coordinated copper(ii) ions in complex 2 indicates intermediate geometry between square pyramidal and trigonal pyramidal geometry. Further, the magnetic measurements have shown antiferromagnetic behaviour of the prepared complexes in a wide range of temperatures. The antiferromagnetic behaviour of 2 should originate from the superexchange interactions between each copper(ii) ion by the mixed chloride and μ

Identifiers

PMID36276031
PMCPMC9516696
OpenAlexW4307230812

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.