ArticleGreen chemistry : an international journal and green chemistry resource : GC2021
Synthesis of performance-advantaged polyurethanes and polyesters from biomass-derived monomers by aldol-condensation of 5-hydroxymethyl furfural and hydrogenation.
Article in Green chemistry : an international journal and green chemistry resource : GC, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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The trial behind it
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Who cites it
8 citing papers in PubMed, 42 citations in OpenAlex.
- From Furfural to Reprocessable Thermosets: Diels-Alder Monomers for Dynamic Polyurethane Networks.ChemSusChem · 2026Review
- Tools for the Design of Diels-Alder-Based Reversible Polymer Systems: Reactivity and Reversibility of Furan/Maleimide Adducts.ACS omega · 2026Article
- Lignin-Based Polyurethanes from the Blocked Isocyanate Approach: Synthesis and Characterization.ACS omega · 2023Article
- Controlling the toxicity of biomass-derived difunctional molecules as potential pharmaceutical ingredients for specific activity toward microorganisms and mammalian cells.Green chemistry : an international journal and green chemistry resource : GC · 2023Article
- Article
- Design of supported organocatalysts from a biomass-derived difuran compound and catalytic assessment for lactose hydrolysis.Green chemistry : an international journal and green chemistry resource : GC · 2023Article
- Controlled hydrogenation of a biomass-derived platform chemical formed by aldol-condensation of 5-hydroxymethyl furfural (HMF) and acetone over Ru, Pd, and Cu catalysts.Green chemistry : an international journal and green chemistry resource : GC · 2022Article
- Design of closed-loop recycling production of a Diels-Alder polymer from a biomass-derived difuran as a functional additive for polyurethanes.Green chemistry : an international journal and green chemistry resource : GC · 2021Article
Corrections and comments
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
Abstract
Functional polyurethanes and polyesters with tunable properties were synthesized from biomass-derived 5-hydroxymethyl furfural (HMF)-Acetone-HMF (HAH) monomers. HAH can be selectively hydrogenated over Cu and Ru catalysts to produce partially-hydrogenated (PHAH) and fully-hydrogenated (FHAH). The HAH units in these polymers improve the thermal stability and stiffness of the polymers compared to polyurethanes produced with ethylene glycol. Polyurethanes produced from PHAH provide diene binding sites for electron deficient C=C double bonds, such as in maleimide compounds, that can participate in Diels-Alder reactions. Such sites can function to create crosslinking by Diels-Alder coupling with bismaleimides and can be used to impart functionality to PHAH (giving rise to anti-microbial activity or controlled drug delivery). The symmetric triol structure of FHAH leads to energy-dissipating rubbers with branched structures. Accordingly, the properties of these biomass-derived polymers can be tuned by controlling the blending ratio of HAH-derived monomers or the degree of Diels-Alder reaction. The polyester produced from HAH can be used in packaging applications.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.