Evidence map›Paper›PMID 36264239›Full record

ArticleThe Journal of organic chemistry2022

Asymmetric Cyclopropanation with 4-Aryloxy-1-sulfonyl-1,2,3-triazoles: Expanding the Range of Rhodium-Stabilized Donor/Acceptor Carbenes to Systems with an Oxygen Donor Group.

Robert W Kubiak, William F Tracy, Joshua S Alford, Huw M L Davies

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in The Journal of organic chemistry, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Generating Fischer-Type Rh-Carbenes with Rh-Carbynoids.Journal of the American Chemical Society · 2023
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Robert W KubiakDepartment of Chemistry, Emory University, 1515 Dickey Dr., Atlanta, Georgia 30329, United States.
William F TracyDepartment of Chemistry, Emory University, 1515 Dickey Dr., Atlanta, Georgia 30329, United States.ORCID 0000-0003-1157-7684
Joshua S AlfordDepartment of Chemistry, Emory University, 1515 Dickey Dr., Atlanta, Georgia 30329, United States.
Huw M L DaviesDepartment of Chemistry, Emory University, 1515 Dickey Dr., Atlanta, Georgia 30329, United States.ORCID 0000-0001-6254-9398

Funding

N-Sulfonyltriazoles as Carbene PrecursorsR01GM099142 · NIGMS · EMORY UNIVERSITY · PI DAVIES, HUW M · 2011 to 2023
$4.1M
NIGMS NIH HHS R01 GM099142
6 · The paper itself

Abstract

Rhodium-catalyzed enantioselective synthesis of 1-phenoxycyclopropane-1-carbaldehydes by intermolecular cyclopropanation of terminal alkenes followed by imine hydrolysis is described. This methodology utilizes 4-aryloxy-1-sulfonyl-1,2,3-triazoles as the carbene precursors and the chiral dirhodium(II) tetracarboxylates Rh

Indexed as

RhodiumCatalysisMethaneMolecular StructureOxygenStereoisomerismTriazoles1-sulfonyl-1,2,3-triazolecarbeneMethaneOxygenRhodiumTriazoles

Identifiers

PMID36264239
PMCPMC10290286

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.