ArticleNature communications2022
Selective activation of four quasi-equivalent C-H bonds yields N-doped graphene nanoribbons with partial corannulene motifs.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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4 citing papers in PubMed.
- Tailoring Electronic Properties of Precision Graphene Nanoribbons via Nanopore Engineering.Angewandte Chemie (International ed. in English) · 2026Article
- Visualizing stepwise evolution of carbon hybridization from spNature communications · 2025Article
- Preferential graphitic-nitrogen formation in pyridine-extended graphene nanoribbons.Communications chemistry · 2024Article
- Room-temperature selective cyclodehydrogenation on Au(111) via radical addition of open-shell resonance structures.Nature communications · 2024Article
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19 authors.
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Abstract
Selective C-H bond activation is one of the most challenging topics for organic reactions. The difficulties arise not only from the high C-H bond dissociation enthalpies but also the existence of multiple equivalent/quasi-equivalent reaction sites in organic molecules. Here, we successfully achieve the selective activation of four quasi-equivalent C-H bonds in a specially designed nitrogen-containing polycyclic hydrocarbon (N-PH). Density functional theory calculations reveal that the adsorption of N-PH on Ag(100) differentiates the activity of the four ortho C(sp
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