Evidence map›Paper›PMID 36251336›Full record

ArticleAngewandte Chemie (International ed. in English)2022

Umpolung Synthesis of Pyridyl Ethers by Bi

Katie Ruffell, Liliana C Gallegos, Kenneth B Ling, Robert S Paton, Liam T Ball

Open access · hybridAbstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
2.2field-weighted citation impact, top 12% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed, 21 citations in OpenAlex.

  1. Article
  2. Ligand-Controlled Chemodivergent Bismuth Catalysis.Journal of the American Chemical Society · 2025
    Article
  3. Article
  4. Article
  5. Article
  6. Article
  7. Umpolung Synthesis of Pyridyl Ethers by BiAngewandte Chemie (International ed. in English) · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors at 3 institutions in 2 countries.

Katie RuffellSchool of Chemistry, University of Nottingham, Nottingham, NG7 2RD, UK.ORCID http://orcid.org/0000-0001-5310-4960
Liliana C GallegosDepartment of Chemistry, Colorado State University, Fort Collins, CO 80523, USA.ORCID http://orcid.org/0000-0002-5291-490X
Kenneth B LingSyngenta, Jealott's Hill International Research Centre, Bracknell, RG42 6EY, UK.
Robert S PatonDepartment of Chemistry, Colorado State University, Fort Collins, CO 80523, USA.ORCID http://orcid.org/0000-0002-0104-4166
Liam T BallSchool of Chemistry, University of Nottingham, Nottingham, NG7 2RD, UK.ORCID http://orcid.org/0000-0003-3849-9006
Colorado State University · USUniversity of Nottingham · GBSyngenta (United Kingdom) · GB

Funding

National Science Foundation 1818253National Science Foundation CHE-1955876Syngenta InternationalUK Research and Innovation MRV0220671
6 · The paper itself

Abstract

We report that O-selective arylation of 2- and 4-pyridones with arylboronic acids is affected by a modular, bismacycle-based system. The utility of this umpolung approach to pyridyl ethers, which is complementary to conventional methods based on S

Indexed as

Ambident NucleophileArylationBismuthDensity-Functional CalculationsSynthetic Methods

Identifiers

PMID36251336
PMCPMC10099949
OpenAlexW4306663595

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.