ArticleBiomacromolecules2022
Stabilized Lignin Nanoparticles for Versatile Hybrid and Functional Nanomaterials.
Article in Biomacromolecules, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- Recovery of Monoethanolammonium Acetate from Ionosolv Liquors Using a γ-Valerolactone-Based Aqueous Two-Phase System.ChemSusChem · 2026Article
- Article
- Article
- Beta-Radiation-Resistant Anticorrosion Coatings Based on Lignin.Small science · 2025Article
- Interfacial Properties of Surface-Modified Lignin Nanoparticles.Langmuir : the ACS journal of surfaces and colloids · 2025Article
- Harnessing Lignin Nanoparticles for Sustainable Enzyme Immobilization: Current Paradigms and Future Innovations.Applied biochemistry and biotechnology · 2025Review
- Lignin-Based Nanocarrier for Simultaneous Delivery ofPharmaceuticals (Basel, Switzerland) · 2025Article
- Biobased Organic Nanoparticles: A Promising Versatile Green Tool for Novel Antimicrobial Agents for Improved Safety.International journal of food science · 2025Review
- Overcoming Challenges of Lignin Nanoparticles: Expanding Opportunities for Scalable and Multifunctional Nanomaterials.Accounts of chemical research · 2024Article
- Article
- Solvent-Induced Lignin Conformation Changes Affect Synthesis and Antibacterial Performance of Silver Nanoparticle.Nanomaterials (Basel, Switzerland) · 2024Article
- Mechanically recyclable melt-spun fibers from lignin esters and iron oxide nanoparticles: towards circular lignin materials.Green chemistry : an international journal and green chemistry resource : GC · 2023Article
- Ag-lignin hybrid nanoparticles for high-performance solar absorption in photothermal antibacterial chitosan films.iScience · 2023Article
- Lignocellulosic Bionanomaterials for Biosensor Applications.Micromachines · 2023Review
- Urushi as a Green Component for Thermally Curable Colloidal Lignin Particles and Hydrophobic Coatings.ACS macro letters · 2023Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Spherical lignin nanoparticles are emerging biobased nanomaterials, but instability and dissolution in organic solvents and aqueous alkali restrict their applicability. Here, we report the synthesis of hydroxymethylated lignin nanoparticles and their hydrothermal curing to stabilize the particles by internal cross-linking reactions. These colloidally stable particles contain a high biobased content of 97% with a tunable particle size distribution and structural stability in aqueous media (pH 3 to 12) and organic solvents such as acetone, ethanol, dimethylformamide, and tetrahydrofuran. We demonstrate that the free phenolic hydroxyl groups that are preserved in the cured particles function as efficient reducing sites for silver ions, giving rise to hybrid lignin-silver nanoparticles that can be used for quick and facile sensing of hydrogen peroxide. The stabilized lignin particles can also be directly modified using base-catalyzed reactions such as the ring-opening of cationic epoxides that render the particles with pH-dependent agglomeration and redispersion properties. Combining scalable synthesis, solvent stability, and reusability, this new class of lignin nanoparticles shows potential for its use in circular biobased nanomaterials.
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