Evidence map›Paper›PMID 36234445›Full record

ArticleNanomaterials (Basel, Switzerland)2022

Tug-of-War Driven by the Structure of Carboxylic Acids: Tuning the Size, Morphology, and Photocatalytic Activity of α-Ag

Lara Kelly Ribeiro, Amanda Fernandes Gouveia, Francisco das Chagas M Silva, Luís F G Noleto, Marcelo Assis, André M Batista, Laécio S Cavalcante, Eva Guillamón, Ieda L V Rosa, Elson Longo and 2 more

Open access · goldAbstract read
In one paragraph

Article in Nanomaterials (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
0.8field-weighted citation impact, top 33% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed, 17 citations in OpenAlex.

  1. Article
  2. Review
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  5. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors at 5 institutions in 2 countries.

Lara Kelly RibeiroPostgraduate Program in Chemistry, Department of Chemistry, Federal University of Piaui, 64049-550, Brazil.
Amanda Fernandes GouveiaDepartment of Physical and Analytical Chemistry, University Jaume I (UJI), 12071 Castellon de La Plana, Spain.ORCID 0000-0003-3441-3674
Francisco das Chagas M SilvaPostgraduate Program in Chemistry, Department of Chemistry, Federal University of Piaui, 64049-550, Brazil.
Luís F G NoletoPostgraduate Program in Chemistry, Department of Chemistry, Federal University of Piaui, 64049-550, Brazil.ORCID 0000-0002-8146-4194
Marcelo AssisLIEC/CDMF, Department of Chemistry, Federal University of São Carlos, P.O. Box 676, 13565-905, Brazil.ORCID 0000-0003-0355-5565
André M BatistaPostgraduate Program in Nanoscience in Advanced Materials, Department of Chemistry, Federal University of ABC, 09210-580, Brazil.ORCID 0000-0001-7450-8139
Laécio S CavalcantePostgraduate Program in Chemistry, Department of Chemistry, State University of Piaui, P.O. Box 381, 64002-150, Brazil.ORCID 0000-0002-0782-4876
Eva GuillamónDepartment of Physical and Analytical Chemistry, University Jaume I (UJI), 12071 Castellon de La Plana, Spain.
Ieda L V RosaLIEC/CDMF, Department of Chemistry, Federal University of São Carlos, P.O. Box 676, 13565-905, Brazil.
Elson LongoLIEC/CDMF, Department of Chemistry, Federal University of São Carlos, P.O. Box 676, 13565-905, Brazil.
Juan AndrésDepartment of Physical and Analytical Chemistry, University Jaume I (UJI), 12071 Castellon de La Plana, Spain.ORCID 0000-0003-0232-3957
Geraldo E Luz JúniorPostgraduate Program in Chemistry, Department of Chemistry, Federal University of Piaui, 64049-550, Brazil.ORCID 0000-0003-4950-6742
Universitat Jaume I · ESUniversidade Federal do Piauí · BRUniversidade Federal de São Carlos · BRUniversidade Estadual do Piauí · BRUniversidade Federal do ABC · BR

Funding

Coordenação de Aperfeicoamento de Pessoal de Nível Superior 88887.353710/2019-00Jaume I University UJI-B2019-30; POSDOC/2019/30National Council for Scientific and Technological Development 001; 305757/2018-0; 312733/2021-6São Paulo Research Foundation 2013/07296-2
6 · The paper itself

Abstract

Size and morphology control during the synthesis of materials requires a molecular-level understanding of how the addition of surface ligands regulates nucleation and growth. In this work, this control is achieved by using three carboxylic acids (tartaric, benzoic, and citric) during sonochemical syntheses. The presence of carboxylic acids affects the kinetics of the nucleation process, alters the growth rate, and governs the size and morphology. Samples synthesized with citric acid revealed excellent photocatalytic activity for the degradation process of Rhodamine B, and recyclability experiments demonstrate that it retains 91% of its photocatalytic activity after four recycles. Scavenger experiments indicate that both the hydroxyl radical and the hole are key species for the success of the transformation. A reaction pathway is proposed that involves a series of dissolution-hydration-dehydration and precipitation processes, mediated by the complexation of Ag

Indexed as

carboxylic acidscontrolled size and morphologyphotocatalytic activitysonochemical synthesisα-Ag2WO4

Identifiers

PMID36234445
PMCPMC9565223
OpenAlexW4297224828

What OpenQuestion holds

Textmetadata
LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.