Evidence map›Paper›PMID 36233947›Full record

ArticleMaterials (Basel, Switzerland)2022

Oxidation of Cyclohexanone with Peracids-A Straight Path to the Synthesis of ε-Caprolactone Oligomers.

Jakub Bińczak, Anna Szelwicka, Agnieszka Siewniak, Krzysztof Dziuba, Anna Chrobok

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Materials (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Review
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Jakub BińczakGrupa Azoty Zakłady Azotowe, "Puławy" S.A., Al. Tysiąclecia Państwa Polskiego 13, 24-110 Puławy, Poland.
Anna SzelwickaDepartment of Chemical Organic Technology and Petrochemistry, Faculty of Chemistry, Silesian University of Technology, Krzywoustego 4, 44-100 Gliwice, Poland.ORCID 0000-0001-8324-856X
Agnieszka SiewniakDepartment of Chemical Organic Technology and Petrochemistry, Faculty of Chemistry, Silesian University of Technology, Krzywoustego 4, 44-100 Gliwice, Poland.ORCID 0000-0003-4780-8798
Krzysztof DziubaGrupa Azoty Zakłady Azotowe, "Puławy" S.A., Al. Tysiąclecia Państwa Polskiego 13, 24-110 Puławy, Poland.
Anna ChrobokDepartment of Chemical Organic Technology and Petrochemistry, Faculty of Chemistry, Silesian University of Technology, Krzywoustego 4, 44-100 Gliwice, Poland.ORCID 0000-0001-7176-7100

Funding

Ministry of Education and Science of Poland DWD/4/21/2020-05/003Silesian University of Technology 04/050/BK_22/0139
6 · The paper itself

Abstract

During Baeyer-Villiger (BV) oxidation of cyclohexanone with peracids, oligo(ε-caprolactone) (OCL) may be formed. In this work, a two-step one-pot method for the synthesis of OCL involving the BV oxidation of cyclohexanone with peracids and then oligomerization of the resulting ε-caprolactone has been developed. The process was carried out in two solvents: toluene and cyclohexane. Based on the studies, it was determined that the increased temperature (45-55 °C) and the longer reaction time (4 h) favor the formation of OCls. Among the tested peracids (perC

Indexed as

Baeyer–Villiger oxidationcyclohexanoneoligomerizationoligo(ε-caprolactone)peracid

Identifiers

PMID36233947
PMCPMC9571306

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.