ArticleThe Journal of organic chemistry2024
Coupled Rocking Motion in a Light-Driven Rotary Molecular Motor.
Article in The Journal of organic chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- General strategy for boosting the performance of speed-tunable rotary molecular motors with visible light.Science advances · 2025Article
- Computational Study on the Dynamics of a Bis(benzoxazole)-Based Overcrowded Alkene.The journal of physical chemistry. A · 2025Article
- Coupling Rotary Motion to Helicene Inversion within a Molecular Motor.Angewandte Chemie (International ed. in English) · 2025Article
- Ligand-controlled regiodivergent arylation of aryl(alkyl)alkynes and asymmetric synthesis of axially chiral 9-alkylidene-9,10-dihydroanthracenes.Nature communications · 2024Article
- A visible-light-driven molecular motor based on barbituric acid.Chemical science · 2023Article
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Coupled motion is ubiquitous in Nature as it forms the base for the direction, amplification, propagation, and synchronization of movement. Herein, we present experimental proof for the coupling of the rocking motion of a dihydroanthracene stator moiety with the light-induced rotational movement of an overcrowded alkene-based molecular motor. The motor was desymmetrized, introducing two different alkyl substituents to the stator part of the molecular scaffold, resulting in the formation of two diastereomers with opposite axial chirality. The structure of the two isomers is determined with nuclear Overhauser effect spectroscopy NMR and single-crystal X-ray analysis. The desymmetrization enables the study of the coupled motion, that is, rotation and oscillation, by
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Registered trials
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