ArticleAngewandte Chemie (International ed. in English)2022
Side-Chain Control of Topochemical Polymer Single Crystals with Tunable Elastic Modulus.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Hierarchical Coordination Polymer-Polymer Composites for Robust, Programmable Photomechanical Actuation.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Beyond geometric constraint: dynamic fluid-lattice-activated topochemical polymerization.National science review · 2026Article
- Force-Induced Selective Carbon-Carbon Bond Cleavage in Mechanoresponsive Topochemical Polymers.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Stiffening Organic Crystals through Polymerization Using Visible Light.Journal of the American Chemical Society · 2025Article
- Topochemical synthesis of chiroptical materials through charge-transfer/Diels-Alder cascade reaction.Nature communications · 2025Article
- Topochemical Ring-Opening Polymerization of an Oxathianethione.Journal of the American Chemical Society · 2025Article
- Continuous production of ultratough semiconducting polymer fibers with high electronic performance.Science advances · 2024Article
- Side-Chain Control of Topochemical Polymer Single Crystals with Tunable Elastic Modulus.Angewandte Chemie (International ed. in English) · 2022Article
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11 authors.
Funding
Abstract
Topochemical polymerizations hold the promise of producing high molecular weight and stereoregular single crystalline polymers by first aligning monomers before polymerization. However, monomer modifications often alter the crystal packing and result in non-reactive polymorphs. Here, we report a systematic study on the side chain functionalization of the bis(indandione) derivative system that can be polymerized under visible light. Precisely engineered side chains help organize the monomer crystals in a one-dimensional fashion to maintain the topochemical reactivity. By optimizing the side chain length and end group of monomers, the elastic modulus of the resulting polymer single crystals can also be greatly enhanced. Lastly, using ultrasonication, insoluble polymer single crystals can be processed into free-standing and robust polymer thin films. This work provides new insights on the molecular design of topochemical reactions and paves the way for future applications of this fascinating family of materials.
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