ArticleProceedings of the Japan Academy. Series B, Physical and biological sciences2022
Phenine design for nanocarbon molecules.
Article in Proceedings of the Japan Academy. Series B, Physical and biological sciences, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Integrating Kinetics into Synthetic Studies via Adaptable Concentration-Dependent Yield Analysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Expanded segments of three-dimensional carbonaceous nets with chirality: synthesis and structures.Chemical science · 2025Article
- Revealing Kinetic Features of a Macrocyclization Reaction Using Machine-Learning-Augmented Data.Angewandte Chemie (International ed. in English) · 2025Article
- Introduction of peripheral nitrogen atoms to cyclo-Beilstein journal of organic chemistry · 2024Article
- Stoichiometry validation of supramolecular complexes with a hydrocarbon cage host by van 't Hoff analyses.Nature communications · 2023Article
- At the dawn of novel aromatics: "On the Synthesis of Hinokitiol" by Tetsuo Nozoe et al.Proceedings of the Japan Academy. Series B, Physical and biological sciences · 2023Article
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Authors and funding
3 authors.
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Abstract
With the name "phenine" given to 1,3,5-trisubstituted benzene for a fundamental trigonal planar unit to weave nanometer-sized networks, a series of curved nanocarbon molecules have been designed and synthesized. Since the 6π-phenine units were amenable to modern biaryl coupling reactions mediated by transition metals, concise syntheses of >400π-nanocarbon molecules were readily achieved. In addition, the phenine design allowed for installing of heteroatoms and/or transition metals doped at specific positions of the large π-systems of the nanocarbon molecules. Fundamental tools were also developed to specify and describe the locations of defects/dopants, quantify pyramidalizations of trigonal panels and estimate molecular Gauss curvatures of the discrete surface. Unique features of phenine nanocarbons, such as stereoisomerism, entropy-driven molecular assembly and effects of dopants on electronic/magnetic characteristics, were revealed during the first half-decade of investigations.
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