ArticleThe journal of physical chemistry letters2022
Molecular Wires for Efficient Long-Distance Triplet Energy Transfer.
Article in The journal of physical chemistry letters, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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Who cites it
1 citing paper in PubMed.
- Excited-State Charge Transfer Coupling from Quasiparticle Energy Density Functional Theory.The journal of physical chemistry letters · 2024Article
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Authors and funding
2 authors.
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Abstract
We propose design rules for building organic molecular bridges that enable coherent long-distance triplet-exciton transfer. Using these rules, we describe example polychromophoric structures with low inner-sphere exciton reorganization energies, low static and dynamic disorder, and enhanced π-stacking interactions between nearest-neighbor chromophores. These features lead to triplet-exciton eigenstates that are delocalized over several units at room temperature. The use of such bridges in donor-bridge-acceptor assemblies enables fast triplet-exciton transport over very long distances that is rate-limited by the donor-bridge injection and bridge-acceptor trapping rates.
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