ArticleAngewandte Chemie (International ed. in English)2022
Crownphyrins: Metal-Mediated Transformations of the Porphyrin-Crown Ether Hybrids.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed, 17 citations in OpenAlex.
- Meso-Crowned Porphyrin as a Dual Cavity Hybrid Macrocycle for Improving the Efficiency and Stability of Perovskite Solar Cells.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- The Interplay Between Component Denticity and Flexibility Promotes the Formation of [AgAngewandte Chemie (International ed. in English) · 2025Article
- Incorporating Two Crown Ether Struts into the Backbone of Robust Zirconium-Based Metal-Organic Frameworks as Custom-Designed Efficient Collectors for Radioactive Metal Ions.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Tying a knot between crown ethers and porphyrins.Beilstein journal of organic chemistry · 2023Article
- Crownphyrins: Metal-Mediated Transformations of the Porphyrin-Crown Ether Hybrids.Angewandte Chemie (International ed. in English) · 2022Article
Corrections and comments
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
Abstract
Crownphyrins are hybrid macrocycles combining structural features of porphyrin and crown ethers. The molecular architecture renders them an intriguing class of hosts capable of binding neutral, and ionic guests. The presence of dynamic covalent imine linkages connecting the dipyrrin segment with the ether chain enables unusual coordination behavior of crownphyrins, as demonstrated by the formation of two classes of strikingly different complexes. The remarkable metal-mediated expansion to the helical [2+2] macrocyclic complex is reversible. The reaction of the figure-eight mercury(II) assembly with [2.2.2]cryptand results in ring contraction providing the metal-free crownphyrin macrocycle.
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Registered trials
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