Evidence map›Paper›PMID 36213958›Full record

ArticleChemSusChem2022

Electrocatalytic Energy Release of Norbornadiene-Based Molecular Solar Thermal Systems: Tuning the Electrochemical Stability by Molecular Design.

Evanie Franz, Daniel Krappmann, Lukas Fromm, Tobias Luchs, Andreas Görling, Andreas Hirsch, Olaf Brummel, Jörg Libuda

Abstract read
In one paragraph

Article in ChemSusChem, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.

0numbers the graph read from it
0cells of the map it votes in
9citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

9 citing papers in PubMed.

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  6. Synthesis and photoinduced switching properties of CBeilstein journal of organic chemistry · 2025
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Evanie FranzInterface Research and Catalysis, Erlangen Center for Interface Research and Catalysis, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058, Erlangen, Germany.ORCID http://orcid.org/0000-0002-2070-0050
Daniel KrappmannChair of Organic Chemistry II, Friedrich-Alexander-Universität Erlangen-Nürnberg, Nikolaus-Fiebiger-Straße 10, 91058, Erlangen, Germany.
Lukas FrommLehrstuhl für Theoretische Chemie, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058, Erlangen, Germany.
Tobias LuchsChair of Organic Chemistry II, Friedrich-Alexander-Universität Erlangen-Nürnberg, Nikolaus-Fiebiger-Straße 10, 91058, Erlangen, Germany.
Andreas GörlingLehrstuhl für Theoretische Chemie, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058, Erlangen, Germany.
Andreas HirschChair of Organic Chemistry II, Friedrich-Alexander-Universität Erlangen-Nürnberg, Nikolaus-Fiebiger-Straße 10, 91058, Erlangen, Germany.
Olaf BrummelInterface Research and Catalysis, Erlangen Center for Interface Research and Catalysis, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058, Erlangen, Germany.ORCID http://orcid.org/0000-0001-5968-0774
Jörg LibudaInterface Research and Catalysis, Erlangen Center for Interface Research and Catalysis, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058, Erlangen, Germany.ORCID http://orcid.org/0000-0003-4713-5941

Funding

Bavarian ministry of Economic Affairs, Regional Development and EnergyDeutsche Forschungsgemeinschaft (DFG) 391585168Deutsche Forschungsgemeinschaft (DFG) 392607742DFG (Collaborative Research Centre SFB 1452 - Catalysis at Liquid Interfaces, Research Unit FOR 1878 "Functional Molecular Structures on Complex Oxide Surfaces" 214951840DFG (Collaborative Research Centre SFB 1452 - Catalysis at Liquid Interfaces, Research Unit FOR 1878 "Functional Molecular Structures on Complex Oxide Surfaces" 322419553DFG (Collaborative Research Centre SFB 1452 - Catalysis at Liquid Interfaces, Research Unit FOR 1878 "Functional Molecular Structures on Complex Oxide Surfaces" 431733372DFG (Collaborative Research Centre SFB 1452 - Catalysis at Liquid Interfaces, Research Unit FOR 1878 "Functional Molecular Structures on Complex Oxide Surfaces" 453560721German Federal ministry of Education and Research 05 K19WE1
6 · The paper itself

Abstract

Molecular solar thermal (MOST) systems, such as the norbornadiene/quadricyclane (NBD/QC) couple, combine solar energy conversion, storage, and release in a simple one-photon one-molecule process. Triggering the energy release electrochemically enables high control of the process, high selectivity, and reversibility. In this work, the influence of the molecular design of the MOST couple on the electrochemically triggered back-conversion reaction was addressed for the first time. The MOST systems phenyl-ethyl ester-NBD/QC (NBD1/QC1) and p-methoxyphenyl-ethyl ester-NBD/QC (NBD2/QC2) were investigated by in-situ photoelectrochemical infrared spectroscopy, voltammetry, and density functional theory modelling. For QC1, partial decomposition (40 %) was observed upon back-conversion and along with a voltammetric peak at 0.6 V

Indexed as

electrochemistryenergy storagephotochemistryphotoswitchessolar thermal fuels

Identifiers

PMID36213958
PMCPMC10099746

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.