ArticleAngewandte Chemie (International ed. in English)2023
Imaging Photoelectron Circular Dichroism in the Detachment of Mass-Selected Chiral Anions.
Article in Angewandte Chemie (International ed. in English), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed, 20 citations in OpenAlex.
- Mass Spectrometry in Chiral Analysis and Synthesis.Chirality · 2026Article
- Spectroscopy and Conformer-Selective Photoelectron Circular Dichroism of Chiral Molecules.Chemistry, an Asian journal · 2026Review
- Induced Photoelectron Circular Dichroism as a Probe for Distinguishing Diastereotopic Lone Electron Pairs.Angewandte Chemie (International ed. in English) · 2026Article
- Linking photoelectron circular dichroism to the asymmetric total photoemission yield measured in aerosol nanoparticles of tyrosine.Nature communications · 2026Article
- Conformer-selective photoelectron circular dichroism: Experimental development and application to nitrogen chirality.Structural dynamics (Melville, N.Y.) · 2025Article
- Determination of the Molar Fraction and Enantiomeric Excess of Electrosprayed Amino Acid Anions Employing Photoelectron Circular Dichroism.Analytical chemistry · 2025Article
- Photoelectron Circular Dichroism in the Photodetachment of Deprotonated 1-Phenylethanol.The journal of physical chemistry letters · 2025Article
- Induced photoelectron circular dichroism onto an achiral chromophore.Nature communications · 2023Article
- Ultrafast control over chiral sum-frequency generation.Science advances · 2023Article
- Fast and precise chiroptical spectroscopy by photoelectron elliptical dichroism.Physical chemistry chemical physics : PCCP · 2023Article
- Imaging Photoelectron Circular Dichroism in the Detachment of Mass-Selected Chiral Anions.Angewandte Chemie (International ed. in English) · 2023Article
Corrections and comments
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
Abstract
Photoelectron Circular Dichroism (PECD) is a forward-backward asymmetry in the photoemission from a non-racemic sample induced by circularly polarized light. PECD spectroscopy has potential analytical advantages for chiral discrimination over other chiroptical methods due to its increased sensitivity to the chiral potential of the molecule. The use of anions for PECD spectroscopy allows for mass-selectivity and provides a path to simple experimental schemes that employ table-top light sources. Evidence of PECD for anions is limited, and insight into the forces that govern PECD electron dynamics in photodetachment is absent. Here, we demonstrate a PECD effect in the photodetachment of mass-selected deprotonated 1-indanol anions. By utilizing velocity map imaging photoelectron spectroscopy with a tunable light source, we determine the energy-resolved PECD over a wide range of photon energies. The observed PECD reaches up to 11 %, similar to what has been measured for neutral species.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.