ArticleNano letters2022
Hot-Carrier Transfer across a Nanoparticle-Molecule Junction: The Importance of Orbital Hybridization and Level Alignment.
Article in Nano letters, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
10 citing papers in PubMed.
- Interfacial Role of DopantNanophotonics (Berlin, Germany) · 2026Article
- 3D nanoprinting of metals by spatiotemporally confined hot electrons via multiple-electron excitations in nanocrystals.Nature communications · 2026Article
- Hot-Carrier Generation in Bimetallic Janus Nanoparticles.ACS nano · 2026Article
- Computational Discovery of Design Principles for Plasmon-Driven Bond Activation on Alloy Antenna Reactors.ACS nano · 2025Article
- Plasmonic Hot-Carrier Engineering at Bimetallic Nanoparticle/Semiconductor Interfaces: A Computational Perspective.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Controlling Plasmonic Catalysis via Strong Coupling with Electromagnetic Resonators.Nano letters · 2024Article
- Hot carriers from intra- and interband transitions in gold-silver alloy nanoparticles.Communications chemistry · 2024Article
- Tailoring Hot-Carrier Distributions of Plasmonic Nanostructures through Surface Alloying.ACS nano · 2024Article
- Advances in fundamentals and application of plasmon-assisted CONanophotonics (Berlin, Germany) · 2024Review
- Recent Advances in Real-Time Time-Dependent Density Functional Theory Simulations of Plasmonic Nanostructures and Plasmonic Photocatalysis.ACS nanoscience Au · 2023Review
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
While direct hot-carrier transfer can increase photocatalytic activity, it is difficult to discern experimentally and competes with several other mechanisms. To shed light on these aspects, here, we model from first-principles hot-carrier generation across the interface between plasmonic nanoparticles and a CO molecule. The hot-electron transfer probability depends nonmonotonically on the nanoparticle-molecule distance and can be effective at long distances, even before a strong chemical bond can form; hot-hole transfer on the other hand is limited to shorter distances. These observations can be explained by the energetic alignment between molecular and nanoparticle states as well as the excitation frequency. The hybridization of the molecular orbitals is the key predictor for hot-carrier transfer in these systems, emphasizing the necessity of ground state hybridization for accurate predictions. Finally, we show a nontrivial dependence of the hot-carrier distribution on the excitation energy, which could be exploited when optimizing photocatalytic systems.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.