ArticleChemical science2022
A comprehensive understanding of carbon-carbon bond formation by alkyne migratory insertion into manganacycles.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed, 16 citations in OpenAlex.
- Revisiting the Gold-Carbon Stretching Frequency: Spectroscopic and Computational Analysis of N-Heterocyclic Carbene Monolayers on Nanostructured Gold Surfaces.Nano letters · 2026Article
- Site-Selective C-H Functionalization on Coumarins Directed by Manganese: Mechanistic Insights from Time-Resolved Spectroscopy and Catalytic Development.ACS organic & inorganic Au · 2026Article
- Intramolecular Vibrational Energy Transfer in the Precatalyst [Mn(ppy)(CO)The journal of physical chemistry. A · 2026Article
- Femtosecond-to-Second Time-Resolved Spectroscopy Brings Unparalleled Insight Into the Life Cycle of the Versatile Manganese Photocatalyst [MnJournal of the American Chemical Society · 2026Article
- Probing Mn Precatalyst Activation through Time-Resolved Spectroscopy: A Quantitative Evaluation of the Effects of CO and PPhInorganic chemistry · 2025Article
- Understanding the Vibrational Structure and Ultrafast Dynamics of the Metal Carbonyl Precatalyst [Mn(ppy)(CO)ACS physical chemistry Au · 2024Article
- The importance of understanding (pre)catalyst activation in versatile C-H bond functionalisations catalysed by [MnChemical science · 2024Article
- Unveiling Mechanistic Complexity in Manganese-Catalyzed C-H Bond Functionalization Using IR Spectroscopy Over 16 Orders of Magnitude in Time.Accounts of chemical research · 2024Article
- Laser induced temperature-jump time resolved IR spectroscopy of zeolites.Chemical science · 2024Article
- Understanding Precatalyst Activation and Speciation in Manganese-Catalyzed C-H Bond Functionalization Reactions.Organometallics · 2023Article
- Coumarin C-H Functionalization by Mn(I) Carbonyls: Mechanistic Insight by Ultra-Fast IR Spectroscopic Analysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- A manganese(i)tricarbonyl-catalyst for near room temperature alkene and alkyne hydroarylation.Chemical science · 2022Article
Corrections and comments
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Authors and funding
9 authors at 3 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Migratory insertion (MI) is one of the most important processes underpinning the transition metal-catalysed formation of C-C and C-X bonds. In this work, a comprehensive model of MI is presented, based on the direct observation of the states involved in the coupling of alkynes with cyclometallated ligands, augmented with insight from computational chemistry. Time-resolved spectroscopy demonstrates that photolysis of complexes [Mn(C^N)(CO)
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.