ArticleAngewandte Chemie (International ed. in English)2022
Energy-Efficient Iodine Uptake by a Molecular Host⋅Guest Crystal.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
5 citing papers in PubMed.
- Anisotropic Swelling of a Single-Crystalline Hydrogen-Bonded Organic Framework Induced by Iodine Vapor Uptake.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Molecular Stiffening by Macrocycle Clustering.Angewandte Chemie (International ed. in English) · 2025Article
- Counteranion-mediated efficient iodine capture in a hexacationic imidazolium organic cage enabled by multiple non-covalent interactions.Nature communications · 2023Article
- Nonporous amorphous superadsorbents for highly effective and selective adsorption of iodine in water.Nature communications · 2023Article
- Energy-Efficient Iodine Uptake by a Molecular Host⋅Guest Crystal.Angewandte Chemie (International ed. in English) · 2022Article
Corrections and comments
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Authors and funding
13 authors.
Funding
Abstract
Recently, porous organic crystals (POC) based on macrocycles have shown exceptional sorption and separation properties. Yet, the impact of guest presence inside a macrocycle prior to adsorption has not been studied. Here we show that the inclusion of trimethoxybenzyl-azaphosphatrane in the macrocycle cucurbit[8]uril (CB[8]) affords molecular porous host⋅guest crystals (PHGC-1) with radically new properties. Unactivated hydrated PHGC-1 adsorbed iodine spontaneously and selectively at room temperature and atmospheric pressure. The absence of (i) heat for material synthesis, (ii) moisture sensitivity, and (iii) energy-intensive steps for pore activation are attractive attributes for decreasing the energy costs.
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Registered trials
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