ArticleChemistry (Weinheim an der Bergstrasse, Germany)2023
Efficient Hydrogenation of N-Heterocycles Catalyzed by NNP-Manganese(I) Pincer Complexes at Ambient Temperature.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed, 36 citations in OpenAlex.
- Computational Exploration of Stereoelectronic Relationships in Manganese-Catalyzed Hydrogenation Reactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Hydrogenation of Terminal Alkenes Catalyzed by Air-Stable Mn(I) Complexes Bearing an N-Heterocyclic Carbene-Based PCP Pincer Ligand.Chemistry (Weinheim an der Bergstrasse, Germany) · 2024Article
- Efficient Hydrogenation of N-Heterocycles Catalyzed by NNP-Manganese(I) Pincer Complexes at Ambient Temperature.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
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Authors and funding
13 authors at 4 institutions in 3 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Manganese-catalyzed hydrogenation reactions have aroused widespread interest in recent years. Among the catalytic systems described, especially PNP- and NNP-Mn pincer catalysts have been reported for the hydrogenation of aldehydes, ketones, nitriles, aldimines and esters. Furthermore, NNP-Mn pincer compounds are efficient catalysts for the hydrogenolysis of less reactive amides, ureas, carbonates, and carbamates. Herein, the synthesis and application of specific imidazolylaminophosphine ligands and the corresponding Mn pincer complexes are described. These new catalysts have been characterized and studied by a combination of experimental and theoretical investigations, and their catalytic activities have been tested in several hydrogenation reactions with good to excellent performance. Especially, the reduction of N-heterocycles can be performed under very mild conditions.
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