ArticleScience advances2022
An "inverse" harpoon mechanism.
Article in Science advances, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Ultrafast Cation-Dication Dynamics in Ammonia Borane: H-Migration to Roaming HThe journal of physical chemistry. A · 2026Article
- Unifying Decoherence and Phase Evolution in Mixed Quantum-Classical Dynamics through Exact Factorization.The journal of physical chemistry letters · 2026Article
- Letter to the Editor Regarding "The Relationship and Mechanisms Between Body Mass Index and Autoimmune Hypothyroidism: Insights from Mendelian Randomization".Obesity surgery · 2025Article
- [Formula: see text]-roaming dynamics in the formation of [Formula: see text] following two-photon double ionization of ethanol and aminoethanol.Scientific reports · 2025Article
- Direct tracking of HNature communications · 2024Article
- Two-Dimensional Projected-Momentum Covariance Mapping for Coulomb Explosion Imaging.The journal of physical chemistry. A · 2024Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Electron-transfer reactions are ubiquitous in chemistry and biology. The electrons' quantum nature allows their transfer across long distances. For example, in the well-known harpoon mechanism, electron transfer results in Coulombic attraction between initially neutral reactants, leading to a marked increase in the reaction rate. Here, we present a different mechanism in which electron transfer from a neutral reactant to a multiply charged cation results in strong repulsion that encodes the electron-transfer distance in the kinetic energy release. Three-dimensional coincidence imaging allows to identify such "inverse" harpoon products, predicted by nonadiabatic molecular dynamics simulations to occur between H
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.