ArticleJournal of the American Chemical Society2022
Solid-State Chemical Recycling of Polycarbonates to Epoxides and Carbon Dioxide Using a Heterodinuclear Mg(II)Co(II) Catalyst.
Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 31 papers.
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Who cites it
31 citing papers in PubMed.
- Depolymerization and Reuse of Polycarbonates: Emerging Classes, Mechanisms and Challenges.Angewandte Chemie (International ed. in English) · 2026Review
- Function Meets Circularity: Metal-Ionomer Cross-Links Toughen and Recycle COMacromolecules · 2026Article
- Quantifying the Influences of Epoxide Binding in Epoxide/COJournal of the American Chemical Society · 2026Article
- All-Round Talent: Unique Zinc Guanidine Catalyst Performs Efficiently in Synthesis and Chemical Recycling of (Bio)Polyesters.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Effects of Molecular Weight Distribution on the Thermal-Mechanical Performance and Recycling of COMacromolecules · 2026Article
- Article
- Chemical Recycling of Polyesters and Polycarbonates: Why Is Zinc(II) Such an Effective Depolymerization Catalyst?Journal of the American Chemical Society · 2025Article
- (AB)Macromolecules · 2025Article
- Recyclable Li-Metal Battery Electrolytes via In Situ Cyclic Carbonate Polymerization.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- The Sustainable Potential of Single-Ion Conducting Polymers.ChemSusChem · 2025Article
- Using Differential Scanning Calorimetry to Accelerate Polymerization Catalysis: A Toolkit for Miniaturized and Automated Kinetics Measurements.ACS catalysis · 2025Article
- From Polymers to Rings and Back Again: Chemical Recycling of Polyesters to Macrolactones.Angewandte Chemie (International ed. in English) · 2025Article
- Circularity in polydiketoenamine thermoplastics via control over reactive chain conformation.Science advances · 2025Article
- Article
- Synergic Catalysis: the Importance of Intermetallic Separation in Co(III)K(I) Catalysts for Ring Opening Copolymerizations.Journal of the American Chemical Society · 2024Article
- Sustainable, Recyclable, and Bench-Stable Catalytic System for Synthesis of Poly(ester-Chem & bio engineering · 2024Article
- Polymer design for solid-state batteries and wearable electronics.Chemical science · 2024Review
- Electrochemical recycling of polymeric materials.Chemical science · 2024Review
- Controlled Carbon Dioxide Terpolymerizations to Deliver Toughened yet Recyclable Thermoplastics.Macromolecules · 2024Article
- Closed-loop recycling of sulfur-rich polymers with tunable properties spanning thermoplastics, elastomers, and vitrimers.Nature communications · 2024Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Polymer chemical recycling to monomers (CRM) could help improve polymer sustainability, but its implementation requires much better understanding of depolymerization catalysis, ensuring high rates and selectivity. Here, a heterodinuclear [Mg(II)Co(II)] catalyst is applied for CRM of aliphatic polycarbonates, including poly(cyclohexene carbonate) (PCHC), to epoxides and carbon dioxide using solid-state conditions, in contrast with many other CRM strategies that rely on high dilution. The depolymerizations are performed in the solid state giving very high activity and selectivity (PCHC, TOF = 25700 h
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Registered trials
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