Evidence map›Paper›PMID 36168797›Full record

ArticleJournal of the American Chemical Society2022

A Covalent Organic Framework for Cooperative Water Oxidation.

Suvendu Karak, Vladimir Stepanenko, Matthew A Addicoat, Philipp Keßler, Simon Moser, Florian Beuerle, Frank Würthner

Open access · greenAbstract read
In one paragraph

Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.

0numbers the graph read from it
0cells of the map it votes in
15citing papers in PubMed
4.4field-weighted citation impact, top 4% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

15 citing papers in PubMed, 63 citations in OpenAlex.

  1. Article
  2. Article
  3. Aqueous and Surfactant-Free Synthesis of Nanoscale Covalent Organic Frameworks.Angewandte Chemie (International ed. in English) · 2026
    Article
  4. Article
  5. Identifying Bottlenecks in the Photocatalytic Oxygen Evolution Reaction with Covalent Organic Frameworks.Chemistry of materials : a publication of the American Chemical Society · 2025
    Article
  6. Article
  7. Article
  8. Article
  9. Article
  10. Article
  11. Article
  12. A Water-Stable Boronate Ester Cage.Journal of the American Chemical Society · 2024
    Article
  13. Article
  14. Review
  15. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors at 2 institutions in 2 countries.

Suvendu KarakInstitut für Organische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, Würzburg 97074, Germany.
Vladimir StepanenkoInstitut für Organische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, Würzburg 97074, Germany.
Matthew A AddicoatSchool of Science and Technology, Nottingham Trent University, Clifton Lane, Nottingham NG11 8NS, U.K.ORCID 0000-0002-5406-7927
Philipp KeßlerPhysikalisches Institut and Würzburg-Dresden Cluster of Excellence ct.qmat, Universität Würzburg, Würzburg D-97074, Germany.
Simon MoserPhysikalisches Institut and Würzburg-Dresden Cluster of Excellence ct.qmat, Universität Würzburg, Würzburg D-97074, Germany.
Florian BeuerleInstitut für Organische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, Würzburg 97074, Germany.ORCID 0000-0001-7239-8327
Frank WürthnerInstitut für Organische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, Würzburg 97074, Germany.ORCID 0000-0001-7245-0471
University of Würzburg · DENottingham Trent University · GB

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The future of water-derived hydrogen as the "sustainable energy source" straightaway bets on the success of the sluggish oxygen-generating half-reaction. The endeavor to emulate the natural photosystem II for efficient water oxidation has been extended across the spectrum of organic and inorganic combinations. However, the achievement has so far been restricted to homogeneous catalysts rather than their pristine heterogeneous forms. The poor structural understanding and control over the mechanistic pathway often impede the overall development. Herein, we have synthesized a highly crystalline covalent organic framework (COF) for chemical and photochemical water oxidation. The interpenetrated structure assures the catalyst stability, as the catalyst's performance remains unaltered after several cycles. This COF exhibits the highest ever accomplished catalytic activity for such an organometallic crystalline solid-state material where the rate of oxygen evolution is as high as ∼26,000 μmol L

Indexed as

Metal-Organic FrameworksWaterHydrogenOxygenPhotosystem II Protein ComplexHydrogenMetal-Organic FrameworksOxygenPhotosystem II Protein ComplexWater

Identifiers

PMID36168797
PMCPMC9523720
OpenAlexW4295896784

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.