Evidence map›Paper›PMID 36167937›Full record

ReviewAngewandte Chemie (International ed. in English)2022

Dynamic Bonds: Adaptable Timescales for Responsive Materials.

Shiwanka V Wanasinghe, Obed J Dodo, Dominik Konkolewicz

Abstract readReview
In one paragraph

Review in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 32 papers.

0numbers the graph read from it
0cells of the map it votes in
32citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

32 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Shiwanka V WanasingheDepartment of Chemistry and Biochemistry, Miami University, 651 East High Street, Oxford, OH 45056, USA.
Obed J DodoDepartment of Chemistry and Biochemistry, Miami University, 651 East High Street, Oxford, OH 45056, USA.
Dominik KonkolewiczDepartment of Chemistry and Biochemistry, Miami University, 651 East High Street, Oxford, OH 45056, USA.ORCID http://orcid.org/0000-0002-3828-5481

Funding

Directorate for Mathematical and Physical Sciences 1749730Miami University Robert H. and Nancy J. Blayney Professorship
6 · The paper itself

Abstract

Dynamic bonds introduce unique properties such as self-healing, recyclability, shape memory, and malleability to polymers. Significant efforts have been made to synthesize a variety of dynamic linkers, creating a diverse library of materials. In addition to the development of new dynamic chemistries, fine-tuning of dynamic bonds has emerged as a technique to modulate dynamic properties. This Review highlights approaches for controlling the timescales of dynamic bonds in polymers. Particularly, eight dynamic bonds are considered, including urea/urethanes, boronic esters, Thiol-Michael exchange, Diels-Alder adducts, transesterification, imine bonds, coordination bonds, and hydrogen bonding. This Review emphasizes how structural modifications and external factors have been used as tools to tune the dynamic character of materials. Finally, this Review proposes strategies for tailoring the timescales of dynamic bonds in polymer materials through both kinetic effects and modulating bond thermodynamics.

Indexed as

Cross-LinkingDynamic BondsDynamic PolymersResponsive MaterialsTuning Dynamic Bonds

Identifiers

PMID36167937
PMCPMC10092857

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.