ArticleThe journal of physical chemistry letters2022
Electron Transfer Rates in Polar and Non-Polar Environments: a Generalization of Marcus' Theory to Include an Effective Treatment of Tunneling Effects.
Article in The journal of physical chemistry letters, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Pursuing Band-like Transport in Colloidal Quantum Dot Assemblies.The journal of physical chemistry letters · 2026Review
- Electron hopping in conjugated molecular wires with application to solar cells.Nature chemistry · 2026Article
- External Reorganization Energy upon Charge Transfer Reactions in Mildly Polar Media: The Case of Naphthalene in Tetrahydrofuran.The journal of physical chemistry letters · 2025Article
- Hole Transfer and the Resulting DNA Damage.Biomolecules · 2024Review
- Charge Localization in Acene Crystals fromThe journal of physical chemistry letters · 2023Article
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Authors and funding
2 authors.
Funding
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Abstract
A multistep kinetic model in which solvent motion is treated in the framework of Marcus theory and the rates of the elementary electron transfer step are evaluated at full quantum mechanical level is proposed and applied to the calculation of the rates of intramolecular electron transfer reactions in rigidly spaced D-Br-A (D = 1,1'-biphenyl radical anion, Br = androstane) compounds, for five acceptors (A) in three organic solvents with different polarity. The calculated rates agree well with experimental ones, and their temperature dependence is almost quantitatively reproduced.
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