Evidence map›Paper›PMID 36165240›Full record

ArticleAngewandte Chemie (International ed. in English)2022

Photoresponsive Dissipative Macrocycles Using Visible-Light-Switchable Azobenzenes.

Esther Nieland, Jona Voss, Andreas Mix, Bernd M Schmidt

Open access · hybridAbstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.

0numbers the graph read from it
0cells of the map it votes in
12citing papers in PubMed
3.0field-weighted citation impact, top 8% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

12 citing papers in PubMed, 41 citations in OpenAlex.

  1. Article
  2. Review
  3. Review
  4. Enhancing the Photoswitching Properties ofJournal of the American Chemical Society · 2025
    Article
  5. Visible-Light Switchable Rings and Chains in Dynamic Covalent Imine Chemistry.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025
    Article
  6. Article
  7. Article
  8. Article
  9. Article
  10. Dynamic covalent synthesis.Chemical science · 2024
    Review
  11. Article
  12. Photoresponsive Dissipative Macrocycles Using Visible-Light-Switchable Azobenzenes.Angewandte Chemie (International ed. in English) · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 2 institutions in 1 country.

Esther NielandInstitut für Organische Chemie und Makromolekulare Chemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstraße 1, 40225, Düsseldorf, Germany.ORCID http://orcid.org/0000-0001-5213-6303
Jona VossInstitut für Organische Chemie und Makromolekulare Chemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstraße 1, 40225, Düsseldorf, Germany.ORCID http://orcid.org/0000-0002-4823-8646
Andreas MixInstitut für Anorganische Chemie und Strukturchemie, Universität Bielefeld, Universitätsstr. 25, 33615, Bielefeld, Germany.
Bernd M SchmidtInstitut für Organische Chemie und Makromolekulare Chemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstraße 1, 40225, Düsseldorf, Germany.ORCID http://orcid.org/0000-0003-3622-8106
Heinrich Heine University Düsseldorf · DEBielefeld University · DE

Funding

Deutsche Forschungsgemeinschaft 417919780Deutsche Forschungsgemeinschaft INST 208/740-1 FUGGDeutsche Forschungsgemeinschaft SCHM 3101/5-1
6 · The paper itself

Abstract

Visible light can be used to shift dynamic covalent imine assemblies out of equilibrium. We studied a fluorinated azobenzene building block that reliably undergoes geometric isomerism upon irradiation. The building block was used in combination with two different amines, ethylenediamine and R,R-1,2-diaminocyclohexane, to create a library of imine macrocycles. Whereas the simple amine can be used to access a polymeric state and a defined bowl-shaped macrocycle, the chiral amine gives access to a rich network of macrocycles that undergo both isomerisation as well as interconversion between different macrocyclic species, thereby allowing for control over the number of monomers involved in the cyclo-oligomerization;

Indexed as

Dynamic Covalent ChemistryIminesPhotochemistrySelf-AssemblySupramolecular Chemistry

Identifiers

PMID36165240
PMCPMC9828355
OpenAlexW4297206797

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.