Evidence map›Paper›PMID 36161749›Full record

ArticleAngewandte Chemie (International ed. in English)2022

Taming Heavier Group 14 Imine Analogues: Accessing Tin Nitrogen [Sn=N] Double Bonds and their Cycloaddition/Metathesis Chemistry.

Malte Fischer, Matthew M D Roy, Lewis L Wales, Mathias A Ellwanger, Caitilin McManus, Aisling F Roper, Andreas Heilmann, Simon Aldridge

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.

0numbers the graph read from it
0cells of the map it votes in
10citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

10 citing papers in PubMed.

  1. Article
  2. Synthesis and One-Electron Reduction of Donor-Acceptor-Stabilized SiAngewandte Chemie (International ed. in English) · 2026
    Article
  3. Isolation and Reactivity of a Stannabismuthene.Angewandte Chemie (International ed. in English) · 2026
    Article
  4. Article
  5. Synthesis, Isolation, and Reactivity of a Phosphinidene Telluride.Angewandte Chemie (International ed. in English) · 2025
    Article
  6. Article
  7. Article
  8. Article
  9. Article
  10. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Malte FischerInorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK.
Matthew M D RoyDepartment of Chemistry, Catalysis Research Center and Institute for Silicon Chemistry, Technische Universität München, 85748, Garching bei München, Germany.
Lewis L WalesInorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK.
Mathias A EllwangerInorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK.
Caitilin McManusInorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK.
Aisling F RoperInorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK.
Andreas HeilmannInorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK.
Simon AldridgeInorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK.ORCID http://orcid.org/0000-0001-9998-9434

Funding

Alexander von Humboldt-StiftungEngineering and Physical Sciences Research Council EP/S023828/1Leverhulme Trust RP-2018-246
6 · The paper itself

Abstract

A systematic study to access stable stannaimines is reported, by combining different heteroleptic stannylenes with a range of organic azides. The reactions of terphenyl-/hypersilyl-substituted stannylenes yield the putative tin nitrogen double bond, but is directly followed by 1,2-silyl migration to give Sn

Indexed as

CycloadditionMain Group ChemistryMetathesisStannaimineTin

Identifiers

PMID36161749
PMCPMC9828258

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.