Evidence map›Paper›PMID 36161683›Full record

ArticleAngewandte Chemie (International ed. in English)2022

Hierarchical Assembly of a Micro- and Macroporous Hydrogen-Bonded Organic Framework with Tailored Single-Crystal Size.

Christopher A Halliwell, Sandra E Dann, Jesus Ferrando-Soria, Felix Plasser, Keith Yendall, Enrique V Ramos-Fernandez, Goran T Vladisavljević, Mark R J Elsegood, Antonio Fernandez

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed.

  1. Rapidly Diversifying Hydrogen-Bonded Organic Frameworks With Permanent Porosity.Angewandte Chemie (International ed. in English) · 2026
    Review
  2. Article
  3. Closed-Loop Recyclable Polyhexahydrotriazine Aerogels Derived From PET Waste.Small (Weinheim an der Bergstrasse, Germany) · 2025
    Article
  4. Article
  5. Article
  6. Article
  7. Review
  8. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Christopher A HalliwellChemistry Department, School of Science, Loughborough University, Loughborough, LE11 3TU, UK.
Sandra E DannChemistry Department, School of Science, Loughborough University, Loughborough, LE11 3TU, UK.
Jesus Ferrando-SoriaICMol, University of Valencia, Valencia, 46980, Spain.ORCID http://orcid.org/0000-0003-0987-2764
Felix PlasserChemistry Department, School of Science, Loughborough University, Loughborough, LE11 3TU, UK.ORCID http://orcid.org/0000-0003-0751-148X
Keith YendallSchool of Aeronautical, Automotive, Chemical and Materials Engineering, AACME), Loughborough University, Loughborough, LE11 3TU, UK.ORCID http://orcid.org/0000-0003-3156-1524
Enrique V Ramos-FernandezLaboratorio de Materiales Avanzados, Departamento de Química Inorgánica-Instituto Universitario de Materiales de Alicante, University of Alicante, Alicante, E-03080, Spain.ORCID http://orcid.org/0000-0001-6357-0383
Goran T VladisavljevićSchool of Aeronautical, Automotive, Chemical and Materials Engineering, AACME), Loughborough University, Loughborough, LE11 3TU, UK.ORCID http://orcid.org/0000-0002-8894-975X
Mark R J ElsegoodChemistry Department, School of Science, Loughborough University, Loughborough, LE11 3TU, UK.ORCID http://orcid.org/0000-0002-8984-4175
Antonio FernandezChemistry Department, School of Science, Loughborough University, Loughborough, LE11 3TU, UK.ORCID http://orcid.org/0000-0002-6626-272X

Funding

MINECO PID2019-104778GB-I00Ministerio de Ciencia e Inovacion PID2020-116998RB-I00Ministerio de Educación y Formación Profesional PRX21/00407
6 · The paper itself

Abstract

Porous organic molecular materials represent an emergent field of research in Chemistry and Materials Science due to their unique combination of properties. To enhance their performance and expand the number of applications, the incorporation of hierarchical porosity is required, as exclusive microporosity entails several limitations. However, the integration of macropores in porous organic molecular materials is still an outstanding challenge. Herein, we report the first example of a hydrogen-bonded organic framework (MM-TPY) with hierarchical skeletal morphology, containing stable micro- and macroporosity. The crystal size, from micro to centimetre scale, can be controlled in a single step without using additives or templates. The mechanism of assembly during the crystal formation is compatible with a skeletal crystal growth. As proof of concept, we employed the hierarchical porosity as a platform for the dual, sequential and selective co-recognition of molecular species and microparticles.

Indexed as

Crystal GrowthHierarchical AssemblyHydrogen-Bonded Organic FrameworksMacroporesMicropores

Identifiers

PMID36161683
PMCPMC9827975

What OpenQuestion holds

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LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.